Fluorination-related TCI Articles

Monofluorination

• Electrophilic Fluorinating Agent, NFBB
• The Deoxyfluorination of Alcohol Using a Photoredox Catalyst
• Fluorination of an Alcohol Using DAST
• Fluorination Using F-TEDA-BF₄
• Synthesis of Aryl Fluorides Using Electrophilic N-F Reagents
• PhenoFluor™ Mix and AlkylFluor™: Stable Reagents for Deoxyfluorinations
• PyFluor: A Stable Deoxyfluorinating Agent
• Hypervalent Iodine-Catalyzed Balz–Schiemann Fluorination
• An Enantioselective Fluorination of α-Branched Aldehydes Using Newly Developed Chiral Amine Catalyst
• An Air- and Moisture- stable Electrophilic Fluorinating Reagent
• Metal-Free Fluorination of C(sp³)-H Bonds using a Catalytic N-Oxyl Radical
• Synthesis of Fluoroalkanes by Deoxygenative Hydrofluorination of Carbonyl Compounds via Their Tosylhydrazones
• Lewis Base Catalyzed Hydrofluorination of Aziridines
• Stereoselective Ring-Opening Hydrofluorination of Aryl Epoxides
• Stable Fluorinating Reagent with Ease of Handling (FLUOLEAD®)

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Trifluoromethylation

• Highly Reactive Electrophilic Trifluoromethylating Reagent: Umemoto Reagent IV
• Trifluoromethylation Catalyzed by Photoredox Catalyst
• Sulfonium Salt Utilized both in Mesitylation and in Trifluoromethylation
• 1,2-(Bis)trifluoromethylation of Arylalkynes Using the Copper Complex
• Visible-Light Photoredox Trifluoromethylation via Perfluoroarene Iodine(III) Reagent Decarboxylaytion
• Morpholine Derivative Usable for Introduction of a Trifluoromethyl Group
• A Photoredox Complex Catalyzed Direct Trifluoromethylation / Chlorination of Alkynes
• Precursor for the preparation of Trifluoromethylcopper Species
• Manganese-catalyzed Aerobic Oxytrifluoromethylation of Styrene Derivatives
• Organoboron Reagent Usable for Trifluoromethylating Reactions
• Trifluoromethylation of Heteroarenes via C-H Bond Activation
• Synthesis of Trifluoromethylketones from Weinreb Amides
• Novel Aromatic Trifluoromethylating Reagent
• Radical Trifluoromethylation using Langlois Reagent
• Oxidative Trifluoromethylation of Indoles
• Electrophilic Trifluoromethylation of Aromatics

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Trifluoromethylthiolation

• Highly Versatile and Atom-Efficient Trifluoromethylthiolating Agent: TTST
• Sulfonamide for Nucleophilic and Electrophilic Trifluoromethylthiolations
• A Versatile and Safe Trifluoromethylthiolating Agent
• Trifluoromethylthiolating Agent Usable for Direct Dehydroxytrifluoromethylthiolation of Alcohols
• Catalytic Trifluoromethylthiolation Using N-(Trifluoromethylthio)phthalimide

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Trifluoromethoxylation

• Safe and Easy-to-handle Trifluoromethoxylating Agent: TFNf

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Difluoromethylation

• Difluoromethylation of Phenols Using Diethyl (Bromodifluoromethyl)phosphonate
• Difluoroacetate Derivative for the Synthesis of Difluoromethylaryls
• Sulfonium Salt for Photo-catalytic Difluoromethylation
• 2-PySO₂CF₂H : Bench-stable Difluoromethylating Agent for Catalytic Difluoromethylation
• Difluoromethylation of Aryl Iodides using a (NHC)Cu(CHF₂) Complex
• An Effective Precursor of a Difluorocarbene to Introduce Difluoromethylene Groups
• Difluoromethylating Reagents
• Difluorocarbene Precursor for Difluoromethylation

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Other Fluorination

• 2,2,2-Trifluoroethyl Etherification Using 2,2,2-Trifluoroethyl p-Toluenesulfonate
• One-Pot Palladium-Catalyzed Fluorosulfonylation of an Aryl Bromide Using DABSO and NFSI
• Difluoroacetate Derivative for the Synthesis of Difluoromethylaryls
• Aziridine Derivative for the Synthesis of a Trifluoroalkylamine Moiety
• Perfluoroalkylation using Perfluoro Acid Anhydrides
• Cross-coupling Reactions of Perfluoroalkyl Zinc Reagents from Perfluoroalkyl Halides
• A New 3,3,3-trifluoropropenylation Reagent, Ikeda–Omote Reagent

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Fluorination-related Product Category Pages

• Fluorination Reagents [Synthetic Reagents]
• Fluorination [Synthetic Reagents]
• Difluoromethylation [Synthetic Reagents]
• Trifluoromethylation [Synthetic Reagents]
• Trifluoromethylthiolation [Synthetic Reagents]
• Other Fluorination Reagents [Synthetic Reagents]
• Fluorinated Building Blocks

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Fluorination-related Product Brochures

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Fluorination-related Useful Links

• [Chem-Station] Nucleophilic Fluoroalkylation
• [Chem-Station] Electrophilic Trifluoromethylation
• [Chem-Station] Amii Trifluoromethylation
• [Organic Chemistry Portal] C-F Bond Formation
• [The Scripps Research Institute] Fluorination of Organic Compounds

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