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CAS RN: 100-97-0 | Product Number: H0093
Hexamethylenetetramine
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Purity: >99.0%(GC)(T)
Synonyms:
- 1,3,5,7-Tetraazaadamantane
- HMTA
- Urotropine
- Methenamine
Product Documents:
| Size | Unit Price | Same Day | 2-3 Business Days |
|---|---|---|---|
| 25G |
₩33,300
|
11 | ≥100 |
| 500G |
₩37,000
|
36 | ≥100 |
* Please contact our distributor of SEJIN CI Co., Ltd.
if you would like to purchase TCI products. The above prices do not include freight cost, customs charge and other charges to the destination. SEJIN CI Co., Ltd. (Phone: 02-2655-2480 / email:
sales@sejinci.co.kr)
* The storage conditions are subject to change without notice.
* The storage conditions are subject to change without notice.
| Product Number | H0093 |
| Purity / Analysis Method | >99.0%(GC)(T) |
| Molecular Formula / Molecular Weight | C__6H__1__2N__4 = 140.19 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| CAS RN | 100-97-0 |
| Reaxys Registry Number | 2018 |
| PubChem Substance ID | 87570541 |
| SDBS (AIST Spectral DB) | 1331 |
| Merck Index (14) | 5966 |
| MDL Number | MFCD00006895 |
Specifications
| Appearance | White powder to crystal |
| Purity(GC) | min. 99.0 % |
| Purity(Nonaqueous Titration) | min. 99.0 % |
| Solubility in Water | almost transparency |
| NMR | confirm to structure |
Properties (reference)
| Melting Point | 280 °C |
| Degree of solubility in water | 448,600 mg/l 12 °C |
| Solubility (soluble in) | Alcohol, Chloroform |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H302 : Harmful if swallowed. H361 : Suspected of damaging fertility or the unborn child. H372 : Causes damage to organs through prolonged or repeated exposure. H317 : May cause an allergic skin reaction. H341 : Suspected of causing genetic defects. H228 : Flammable solid. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P272 : Contaminated work clothing should not be allowed out of the workplace. P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P202 : Do not handle until all safety precautions have been read and understood. P240 : Ground/bond container and receiving equipment. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P201 : Obtain special instructions before use. P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P308 + P313 : IF exposed or concerned: Get medical advice/ attention. P362 + P364 : Take off contaminated clothing and wash it before reuse. P333 + P313 : If skin irritation or rash occurs: Get medical advice/ attention. P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. P405 : Store locked up. |
Related Laws:
| RTECS# | MN4725000 |
Transport Information:
| UN Number | UN1328 |
| Class | 4.1 |
| Packing Group | III |
| H.S.code* | 2933.99-000 |
Application
TCI Practical Example: Formylation Using Hexamethylenetetramine (= Duff reaction)
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Used Chemicals
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- 2,6-Dimethylphenol [D0776]
- Hexamethylenetetramine [H0093]
- Trifluoroacetic Acid (= TFA)
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Procedure
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A solution of 2,6-dimethylphenol (500 mg, 4.1 mmol) and hexamethylenetetramine (574 mg, 4.1 mmol) in TFA (5 mL) was stirred under nitrogen at 80 ˚C for 1.5 hours. The reaction was quenched with water and extracted with diethyl ether. The organic phase was dried over anhydrous sodium sulfate and filtered. The solvent was removed under reduced pressure to give 4-hydroxy-3,5-dimethylbenzaldehyde as a yellow solid (446 mg, 73% yield).
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Analytical Data
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The reaction mixture was monitored by NMR.
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Analytical Data
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4-Hydroxy-3,5-dimethylbenzaldehyde
1H NMR (270 MHz, CDCl3); δ 9.81 (s, 1H), 7.55 (s, 2H), 5.28 (bs, 1H), 2.31 (s, 6H).
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Lead Reference
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- Electronic-State Switching Strategy in the Photochemical Synthesis of Indanones from o-Methyl Phenacyl Epoxides
Application
Duff Reaction
References
- Electronic-State Switching Strategy in the Photochemical Synthesis of Indanones from o-Methyl Phenacyl Epoxides
PubMed Literature
Articles/Brochures
TCIMAIL
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Safety Data Sheet (SDS)
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Specifications
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