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CAS RN: 100-97-0 | Product Number: H0093
Hexamethylenetetramine
×
Purity: >99.0%(GC)(T)
Synonyms:
- 1,3,5,7-Tetraazaadamantane
- HMTA
- Urotropine
- Methenamine
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
Shipping Information
|
|---|---|---|---|---|---|---|
| 25G |
$24.00
|
7 | 4 | ≥100 |
|
|
| 500G |
$32.00
|
23 | 3 | ≥100 |
|
* Items in stock locally typically ship the same day of ordering. Items from Japan stock are able to ship from a US warehouse within 2 weeks after ordering. For additional estimated shipment times, please refer to the Shipping Simulation tool. Note: Excludes regulated items and items that ship on ice.
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*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | H0093 |
Purity / Analysis Method 
|
>99.0%(GC)(T) |
| Molecular Formula / Molecular Weight | C__6H__1__2N__4 = 140.19 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| CAS RN | 100-97-0 |
| Reaxys Registry Number | 2018 |
| PubChem Substance ID | 87570541 |
| SDBS (AIST Spectral DB) | 1331 |
| Merck Index (14) | 5966 |
| MDL Number | MFCD00006895 |
Specifications
| Appearance | White powder to crystal |
| Purity(GC) | min. 99.0 % |
| Purity(Nonaqueous Titration) | min. 99.0 % |
| Solubility in Water | almost transparency |
| NMR | confirm to structure |
Properties (reference)
| Melting Point | 280 °C |
| Degree of solubility in water | 448,600 mg/l 12 °C |
| Solubility (soluble in) | Chloroform, Alcohol |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H302 : Harmful if swallowed. H361 : Suspected of damaging fertility or the unborn child. H372 : Causes damage to organs through prolonged or repeated exposure. H317 : May cause an allergic skin reaction. H341 : Suspected of causing genetic defects. H228 : Flammable solid. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P202 : Do not handle until all safety precautions have been read and understood. P240 : Ground/bond container and receiving equipment. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P201 : Obtain special instructions before use. P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P272 : Contaminated work clothing must not be allowed out of the workplace. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P308 + P313 : IF exposed or concerned: Get medical advice/ attention. P302 + P352 : IF ON SKIN: Wash with plenty of soap and water. P333 + P313 : If skin irritation or rash occurs: Get medical advice/ attention. P363 : Wash contaminated clothing before reuse. P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. P405 : Store locked up. |
Related Laws:
| RTECS# | MN4725000 |
Transport Information:
| UN Number (DOT-AIR) | UN1328 |
| Class (DOT-AIR) | 4.1 |
| Packing Group (TCI-A) | III |
| HS Number | 2933.99.9701 |
Application
TCI Practical Example: Formylation Using Hexamethylenetetramine (= Duff reaction)
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Used Chemicals
-
- 2,6-Dimethylphenol [D0776]
- Hexamethylenetetramine [H0093]
- Trifluoroacetic Acid (= TFA)
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Procedure
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A solution of 2,6-dimethylphenol (500 mg, 4.1 mmol) and hexamethylenetetramine (574 mg, 4.1 mmol) in TFA (5 mL) was stirred under nitrogen at 80 ˚C for 1.5 hours. The reaction was quenched with water and extracted with diethyl ether. The organic phase was dried over anhydrous sodium sulfate and filtered. The solvent was removed under reduced pressure to give 4-hydroxy-3,5-dimethylbenzaldehyde as a yellow solid (446 mg, 73% yield).
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Analytical Data
-
The reaction mixture was monitored by NMR.
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Analytical Data
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4-Hydroxy-3,5-dimethylbenzaldehyde
1H NMR (270 MHz, CDCl3); δ 9.81 (s, 1H), 7.55 (s, 2H), 5.28 (bs, 1H), 2.31 (s, 6H).
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Lead Reference
-
- Electronic-State Switching Strategy in the Photochemical Synthesis of Indanones from o-Methyl Phenacyl Epoxides
Application
Duff Reaction
References
- Electronic-State Switching Strategy in the Photochemical Synthesis of Indanones from o-Methyl Phenacyl Epoxides
PubMed Literature
Documents
Product Articles
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Safety Data Sheet (SDS)
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Specifications
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