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Maximum quantity allowed is 999
CAS RN: 114615-82-6 | Product Number: T1559
Tetrapropylammonium Perruthenate
Purity:
- TPAP
Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
---|---|---|---|---|---|
1G |
$157.00
|
2 | 1 | ≥60 |
|
5G |
$456.00
|
1 | Contact Us | ≥100 |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
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*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
Product Number | T1559 |
Molecular Formula / Molecular Weight | C__1__2H__2__8NO__4Ru = 351.43 |
Physical State (20 deg.C) | Solid |
Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
Store Under Inert Gas | Store under inert gas |
Condition to Avoid | Hygroscopic |
Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image) |
CAS RN | 114615-82-6 |
Reaxys Registry Number | 13168949 |
PubChem Substance ID | 87577317 |
MDL Number | MFCD00074914 |
Appearance | Dark green to Dark blue to Black powder to crystal |
Functionality test | to pass test |
Melting Point | 163 °C(dec.) |
Pictogram | |
Signal Word | Warning |
Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H272 : May intensify fire; oxidizer. |
Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P220 : Keep/Store away from clothing/ combustible materials. P210 : Keep away from heat. P221 : Take any precaution to avoid mixing with combustibles. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302 + P352 : IF ON SKIN: Wash with plenty of soap and water. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P362 : Take off contaminated clothing and wash before reuse. |
UN Number (DOT-AIR) | UN1479 |
Class (DOT-AIR) | 5.1 |
Packing Group (TCI-A) | III |
HS Number | 2923.90.0100 |
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Used Chemicals
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Procedure
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To a suspension of trans-2-phenyl-1-cyclohexanol (68.3 mg, 0.39 mmol), NMO (104.7 mg, 0.89 mmol), MS4A (156 mg) in dichloromethane (2.8 mL) was added TPAP (10.0 mg, 0.03 mmol) at room temperature and the mixture was stirred for 3 hours. After the addition of MS4A (220 mg), the reaction mixture was stirred at room temperature for overnight. Then the mixture was directly purified by column chromatography (on silica gel, ethyl acetate:hexane = 0:1 - 9:91), giving 2-phenylcyclohexane (58.4 mg, 87% yield) as a white solid.
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Experimenter’s Comments
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The reaction mixture was monitored by TLC (ethyl acetate:hexane = 2:1, Rf = 0.70).
TPAP and NMO were weighed quickly due to their hygroscopicity.
MS4A was heated and dried using a heat gun under reduced pressure before use.
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Analytical Data
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2-Phenylcyclohexanone
1H NMR (270 MHz, CDCl3); δ 7.37-7.22 (m, 3H), 7.16-7.13 (m, 2H), 3.61 (dd, J = 5.4, 11.6 Hz, 1 H), 2.58-2.39 (m, 2H), 2.33-2.78 (m, 6H).
13C NMR (67.8 MHz, CDCl3); δ 210.3, 138.7, 128.5 (2C), 128.3 (2C), 126.9, 57.4, 42.2, 35.1, 27.8, 25.3.
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Other References
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- Preparation and use of tetra-n-butylammonium per-ruthenate (TBAP reagent) and tetra-n-propylammonium per-ruthenate (TPAP reagent) as new catalytic oxidants for alcohols
References
- W. P. Griffith, S. V. Ley, G. P. Whitcombe, A. D. White, J. Chem. Soc., Chem. Commun. 1987, 1625.
- N. J. Anthony, A. Armstrong, S. V. Ley, A. Madin, Tetrahedron Lett. 1989, 30, 3209.
Articles/Brochures
Safety Data Sheet (SDS)
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Specifications
C of A & Other Certificates
Sample C of A
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Analytical Charts
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