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CAS RN: 13292-87-0 | 產品號碼: D1843
Dimethyl Sulfide Borane
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25mL and 100mL bottle of this product are attached with a DualSeal (Septum-type Bottle Cap).
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| 產品號碼 | D1843 |
| 純度/分析方法 | >90.0%(T) |
| 分子式 / 分子量 | C__2H__6S·BH__3 = 75.96 |
| 外觀與形狀（20°C） | Liquid |
| 儲存條件 | Refrigerated (0-10°C) |
| 儲存在惰性氣體下 | Store under inert gas |
| 應避免的情況 | Air Sensitive,Moisture Sensitive,Heat Sensitive |
| 包裝和容器 | 100ML-DualSeal Bottle （閲覽圖片）, 25ML-DualSeal Bottle （閲覽圖片） |
| CAS RN | 13292-87-0 |
| Reaxys-RN | 3663489 |
| PubChem Substance ID | 87568309 |
| MDL編號 | MFCD00013189 |
產品規格
| Appearance | Colorless to Light yellow clear liquid |
| Purity(Neutralization titration) | min. 90.0 % |
| NMR | confirm to structure |
性質
| flp | 18 °C |
| 比重 | 0.80 |
| 折射率 | 1.46 |
GHS
| 圖形表示 |
|
| 信號詞 | Danger |
| 危險性說明 | H318 : Causes serious eye damage. H225 : Highly flammable liquid and vapor. H260 : In contact with water releases flammable gases which may ignite spontaneously. |
| 防範說明 | P501 : Dispose of contents/ container to an approved waste disposal plant. P223 : Do not allow contact with water. P240 : Ground/bond container and receiving equipment. P231 + P232 : Handle under inert gas. Protect from moisture. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 : Keep container tightly closed. P243 : Take precautionary measures against static discharge. P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 : Use only non-sparking tools. P280 : Wear protective gloves/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P335 + P334 : Brush off loose particles from skin. Immerse in cool water/ wrap in wet bandages. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P402 + P404 : Store in a dry place. Store in a closed container. P403 + P235 : Store in a well-ventilated place. Keep cool. |
相關法規
| RTECS # | PV5080000 |
運輸資料
| UN編號 | UN3399 |
| 類別 | 4.3 / 3 |
| 包裝類別 | I |
| HS編碼* | 2930.90-900 |
Application
A Stereoselective Hydroamination Transform To Access Polysubstituted Indolizidines
Reference
Application
Hydroboration
References
- S. Saito, T. Hasegawa, M. Inaba, R. Nishida, T. Fujii, S. Nomizu, T. Moriwake, Chem. Lett. 1984, 1389.
- L. M. Braun, R. A. Braun, H. R. Crissman, M. Opperman, R. M. Adams, J. Org. Chem. 1971, 36, 2388.
- C. F. Lane, J. Org. Chem. 1974, 39, 1437.
- R. O. Hutchins, F. Cistone, Org. Prep. Proced. Int. 1981, 13, 225.
- C. F. Lane, J. J. Daniels, Org. Synth. Coll. Vol. 1988, 6, 719.
- H. C. Brown, J. V. N. Vara Prasad, S-H. Zee, J. Org. Chem. 1986, 51, 439.
考研文獻
Please visit the Pubchem page at this link.
文章/手冊
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