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CAS RN: 894102-11-5 | 產品號碼: B3354
Bromo[(2,6-pyridinediyl)bis(3-methyl-1-imidazolyl-2-ylidene)]nickel Bromide
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產品號碼 | B3354 |
純度/分析方法 | >98.0%(T)(N) |
分子式 / 分子量 | C__1__3H__1__3Br__2N__5Ni = 457.78 |
外觀與形狀(20°C) | Solid |
儲存條件 | Room Temperature (Recommended in a cool and dark place, <15°C) |
儲存在惰性氣體下 | Store under inert gas |
應避免的情況 | Moisture Sensitive |
包裝和容器 | 1G-Glass Bottle with Plastic Insert (閲覽圖片) |
CAS RN | 894102-11-5 |
PubChem Substance ID | 87561048 |
產品規格
Appearance | Orange to Amber to Dark red powder to crystal |
Purity(with Total Nitrogen) | min. 98.0 % |
Purity(Chelometric Titration) | min. 98.0 % |
性質
GHS
圖形表示 |
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信號詞 | Danger |
危險性說明 | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H372 : Causes damage to organs through prolonged or repeated exposure. H317 : May cause an allergic skin reaction. H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled. H350 : May cause cancer. |
防範說明 | P501 : Dispose of contents/ container to an approved waste disposal plant. P272 : Contaminated work clothing should not be allowed out of the workplace. P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P202 : Do not handle until all safety precautions have been read and understood. P201 : Obtain special instructions before use. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 : Wear respiratory protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P308 + P313 : IF exposed or concerned: Get medical advice/ attention. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P304 + P340 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. P333 + P313 : If skin irritation or rash occurs: Get medical advice/ attention. P405 : Store locked up. |
相關法規
運輸資料
HS編碼* | 2933.39-000 |
Application
Kumada-Tamao-Corriu Cross-Coupling Reaction
References
- Catalytic Activities of a Bis(carbene)-Derived Nickel(II)-Pincer Complex in Kumada-Tamao-Corriu and Suzuki-Miyaura Coupling Reactions for the Synthesis of Biaryl Compounds
Application
Suzuki-Miyaura Cross-Coupling Reaction
References
- Synthesis and Catalytic Activity of a Pincer-Type Bis(imidazolin-2-ylidene) Nickel(II) Complex
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