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CAS RN: 617-86-7 | 产品编码: T0662

Triethylsilane

纯度/分析方法: >98.0%(GC)

别名：

三乙基硅烷

产品文档：

规格	单价	同一天	2-3个工作日	左侧以上货期	数量	货期信息
25ML	S$88.50	≥100	≥100	下单后约2周内可以发货		货期预估
250ML	S$445.50	8	≥100	下单后约3-4周内可以发货		货期预估

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补充产品信息:

Both 250mL bottles of this product is attached with a DualSeal (Septum-type Bottle Cap).
For details, please refer to the page "DualSeal (Septum-type Bottle Cap)".

基本信息

产品编码	T0662
纯度/分析方法	>98.0%(GC)
分子式/分子量	C₆H₁₆Si = 116.28
外观与形状（20°C）	液体
储存温度	室温 (15°C以下阴凉干燥处)
储存在惰性气体下	存放于惰性气体之中
应避免的情况	湿气 (分解)
包装和容器	250ML-DualSeal Bottle （查看图片）
CAS RN	617-86-7
Reaxys-RN	1098278
PubChem物质ID	87576536
SDBS (AIST Spectral DB)	15771
MDL编号	MFCD00009018

质量规格/物性

安全和法规

GHS

象形图
信号词	Danger
危险性说明	H315 : Causes skin irritation. H319 : Causes serious eye irritation. H225 : Highly flammable liquid and vapor.
防范说明	P501 : Dispose of contents/ container to an approved waste disposal plant. P240 : Ground/bond container and receiving equipment. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 : Keep container tightly closed. P243 : Take precautionary measures against static discharge. P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 : Use only non-sparking tools. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P403 + P235 : Store in a well-ventilated place. Keep cool.

Reference

Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols
- P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.

应用

3-Position Selective Bn Cleavage of Cyclodextrins using Iodine and Triethylsilane

Reference

Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols
- P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.

应用

Reduction of Ethanethiol Esters to Aldehydes (Fukuyama Reduction)

Typical procedure: A 200 mL flask is charged with Cbz-L-phenylalanine ethanethiol ester (20 g), 10 % Pd/C (3.1 g) and acetone (58 mL) under an argon atmosphere. To the suspension is added triethylsilane (13.9 mL) over 1 h at rt. The completion of the reduction can be checked by TLC. The solvent is carefully removed on a rotary evaporator. The residue is suspended in diethylether (60 mL) and the catalyst is filtered off through a Celite pad and rinsed with diethylether (6 x 20 mL). The filtrate is concentrated under reduced pressure to give a crude oil, which solidified upon addition of hexane (30 mL). The solid is collected by filtration and washed with cooled hexane (7 x 10 mL) to give Cbz-L-phenylalaninal (11.6 g, 70.3 %).

References

应用

Mild Reducing Agent

Reference

J. D. Citron, J. Org. Chem. 1969, 34, 1977.

参考文献

文章/手册

氨基酸和肽研究用试剂

Carbon Monoxide (CO) Surrogate Reagents for Carbonylation

硅化合物

TCIMail

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低聚糖合成试剂 [糖科学]

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Appearance	Colorless to Almost colorless clear liquid
Purity(GC)	min. 98.0 %
NMR	confirm to structure

沸点	108 °C
闪点	-3 °C
比重	0.73
折射率	1.41

UN编号	UN1993
类别	3
包装类别	II
HS编码*	2931.90-000

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CAS RN: 617-86-7 | 产品编码: T0662

Triethylsilane

Reference

Reference

References

Reference

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化学品安全说明书(SDS)

技术规格

CoA及其他文档

示例 CoA

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CAS RN: 617-86-7 | 产品编码: T0662

Triethylsilane

Reference

Reference

References

Reference

文章/手册

化学品安全说明书(SDS)

技术规格

CoA及其他文档

示例 CoA

分析图谱

其他文件

产品类别

化学结构

化学

生命科学

化学结构

化学

生命科学