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CAS RN: 104439-77-2 | 产品编码: H1322
1-Hydroxytetraphenylcylclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II)
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| 产品编码 | H1322 |
| 分子式/分子量 | C__6__2H__4__2O__6Ru__2 = 1,085.15 |
| 外观与形状（20°C） | 固体 |
| 储存温度 | 室温 (15°C以下阴凉干燥处) |
| 储存在惰性气体下 | 存放于惰性气体之中 |
| 应避免的情况 | 空气,湿气 (分解) |
| 包装和容器 | 100MG-Glass Bottle with Plastic Insert （查看图片） |
| CAS RN | 104439-77-2 |
| PubChem物质ID | 125308084 |
| Merck Index (14) | 8483 |
| MDL编号 | MFCD03840556 |
技术规格
| Appearance | Light yellow to Brown powder to crystal |
| Elemental analysis(Carbon) | 67.0 to 71.0 % |
物性（参考值）
| 熔点 | 227 °C |
GHS
相关法规
运输信息
| HS编码* | 2843.90-000 |
应用
Reviews
References
- Shvo's diruthenium complex: a robust catalyst
- Discovery, Applications, and Catalytic Mechanisms of Shvo’s Catalyst
应用
Anti-Markovnikov Hydration of Vinylarenes via Triple Relay Catalysis
Typical procedure (R = H): PdCl2(CH3CN)2 (10.4 mg), Shvo’s catalyst (43.6 mg), CuCl2 (10.8 mg) and 1,4-benzoquinone (43.2 mg) are weighed into a 20 mL vial under a nitrogen atmosphere, followed by the addition of i-PrOH (2 mL) and t-BuOH (4 mL). Styrene (41.7 mg) is added to the mixture followed by addition of H2O (8.1 µL). After the resulting mixture is stirred at 85 °C for 6 h, it is diluted with pentane (6 mL) and filtered through a plug of silica gel followed by flushing with ethyl acetate (6 mL). The solvent is removed under vacuum, and the residue is purified by silica gel flash chromatography to give 2-phenylethyl alcohol (41 mg, 87 % yield).
References
应用
Synthesis of Aromatic Amines under Catalytic Transfer Hydrogenation Conditions
Typical procedure (entry 1): In a pressure tube under an argon atmosphere, the Shvo’s catalyst (22 mg), p-toluidine (429 mg), and hexylamine (202 mg) are dissolved in tert-amyl alcohol (0.5 ml). The pressure tube is fitted with a polytetrafluoroethylene cap and heated at 150 °C for 24 h in an oil bath. The solvent is removed in vacuo, and the crude product is purified by column chromatography (eluent: pentane/ethyl acetate) to give N-hexyl-4-methylaniline as colorless crystals (374 mg, 98 %).
References
参考文献
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