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CAS RN: 1414707-08-6 | 产品编码: A3009
AquaMet
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纯度/分析方法: >95.0%(HPLC)
别名：
- [1,3-双(2,4,6-三甲基苯基)-4-[(4-乙基-4-甲基哌嗪鎓-1-基)甲基]-2-咪唑啉亚基]二氯(2-异丙氧苯亚甲基)氯化钌(II)
- [1,3-Bis(2,4,6-trimethylphenyl)-4-[(4-ethyl-4-methylpiperazinium-1-yl)methyl]-2-imidazolidinylidene]dichloro(2-isopropoxybenzylidene)ruthenium(II) Chloride
产品文档：
| 规格 | 单价 | 同一天 | 2-3个工作日 | 数量 |
|---|---|---|---|---|
| 100MG |
S$255.00
|
9 | 请联系我们 |
|
| 500MG |
S$892.50
|
2 | 6 |
|
补充产品信息:
Sold in collaboration with Apeiron Synthesis.
PCT/EP2013/053967
| 产品编码 | A3009 |
| 纯度/分析方法 | >95.0%(HPLC) |
| 分子式/分子量 | C__3__9H__5__5Cl__3N__4ORu = 803.32 |
| 外观与形状（20°C） | 固体 |
| 储存温度 | 冷藏 (0-10°C) |
| 储存在惰性气体下 | 存放于惰性气体之中 |
| 应避免的情况 | 湿气 (吸湿),加热 |
| 包装和容器 | 100MG-Glass Bottle with Plastic Insert （查看图片）, 500MG-Glass Bottle with Plastic Insert （查看图片） |
| CAS RN | 1414707-08-6 |
| Reaxys-RN | 27464286 |
| PubChem物质ID | 354334182 |
| MDL编号 | MFCD28411647 |
技术规格
| Appearance | Light yellow to Amber to Dark green powder to crystal |
| Purity(HPLC) | min. 95.0 area% |
物性（参考值）
GHS
相关法规
运输信息
| HS编码* | 2843.90-000 |
应用
TCI Practical Example: Olefin Metathesis
Used Chemicals
- Diethyl Diallylmalonate [D1183]
- AquaMet [A3009]
- Dichloromethane
Procedure
-
In a 200 mL two necked round bottomed flask, AquaMet (50 mg, 52 μmol) was added, and purged with N2. Dichloromethane (100 mL) was charged in the flask, and diethyl diallylmalonate (500 mg, 2.08 mmol) in dichloromethane (20 mL) was added dropwise and the mixture was stirred at room temperature for 6 h. The solvent was removed under reduced pressure and the residue was purified by silica-gel column chromatography (hexane : EtOAc = 1 : 1) to give diethyl cyclopent-3-ene-1,1-dicarboxylate as a pale yellow oil (430 mg, 98%).
Experimenter's Comments
The reaction mixture was monitored by NMR.
Analytical Data（Diethyl cyclopent-3-ene-1,1-dicarboxylate）
1H NMR (400 MHz, CDCl3); δ 5.61 (s, 2H), 4.20 (q, J = 8.0 Hz, 4H), 3.01 (s, 4H), 1.25 (t, J = 8.0 Hz, 6H).
Lead Reference
- Nitro-Substituted Hoveyda−Grubbs Ruthenium Carbenes: Enhancement of Catalyst Activity through Electronic Activation
应用
Metathesis Catalyst Usable in Water Media
Flask equipped with a magnetic stirring bar is charged with Z-olefin (8.7 mg, 0.15 mmol) and non-degassed D2O (1.5 ml). Next to this solution AquaMet (0.6 mg, 0.75 µmol) is added. Reaction mixture is stirred at 25 °C for 1.1 h. Next 0.7 ml of reaction mixture is transferred to an NMR tube. Yield of a product (71%) is determined using NMR method.
References
- Highly active catalysts for olefin metathesis in water
应用
Ring Closing Metathesis in Water Media
References
- Highly active catalysts for olefin metathesis in water
应用
Mesoporous Silica Supported Metathesis Catalyst
References
- Ru-based complexes with quaternary ammonium tag immobilized on mesoporous silica as olefin metathesis catalysts
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