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可在水中使用的复分解催化剂
Grela 等人开发出的AquaMet是一种Hoveyda-型复分解催化剂,其含有一个季铵盐官能团,因此适用于水相体系。AquaMet催化剂可以应用于Z-型烯烃或端烯的分子间复分解反应,从而合成出相应的E-型烯烃。同样的,1,6-二烯或烯炔也可以通过关环复分解得到中等产率的环烯1)。 另外,借助季铵盐基团和二氧化硅的亲核性,AquaMet还可以负载在介孔氧化硅上用作载体催化剂2)。
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- 1) Highly active catalysts for olefin metathesis in water
- 2) Ru-based complexes with quaternary ammonium tag immobilized on mesoporous silica as olefin metathesis catalysts