text.skipToContent text.skipToNavigation

Maximum quantity allowed is 999

Please select the quantity

CAS RN: 593-60-2 | Product Number: V0127

Vinyl Bromide (ca. 12% in Tetrahydrofuran, ca. 1.0mol/L)


Purity:
Synonyms:
  • Bromoethylene (ca. 12% in Tetrahydrofuran, ca. 1.0mol/L)
Product Documents:
100ML
S$160.50
4   ≥100  Contact Us

* Please contact our distributors or TCI to order TCI products.
* The storage conditions are subject to change without notice.


Supplemental Product Information:

100mL bottle of this product is attached with a DualSeal (Septum-type Bottle Cap).
For details, please refer to the page "DualSeal (Septum-type Bottle Cap)".

Product Number V0127
Molecular Formula / Molecular Weight C__2H__3Br = 106.95 
Physical State (20 deg.C) Liquid
Storage Temperature Refrigerated (0-10°C)
Store Under Inert Gas Store under inert gas
Condition to Avoid Light Sensitive,Air Sensitive,Heat Sensitive
Packaging and Container 100ML-DualSeal Bottle (View image)
CAS RN 593-60-2
Reaxys Registry Number 1361370
PubChem Substance ID 253661892
MDL Number

MFCD00000183

Specifications
Appearance Colorless to Almost colorless clear liquid
Concentration(HNMR) 11.5 to 12.5 w/w%
NMR confirm to structure
Properties (reference)
GHS
Pictogram Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H302 : Harmful if swallowed.
H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H371 : May cause damage to organs.
H372 : Causes damage to organs through prolonged or repeated exposure.
H341 : Suspected of causing genetic defects.
H350 : May cause cancer.
H335 : May cause respiratory irritation.
H225 : Highly flammable liquid and vapor.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
P270 : Do not eat, drink or smoke when using this product.
P202 : Do not handle until all safety precautions have been read and understood.
P240 : Ground/bond container and receiving equipment.
P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 : Keep container tightly closed.
P201 : Obtain special instructions before use.
P243 : Take precautionary measures against static discharge.
P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P242 : Use only non-sparking tools.
P271 : Use only outdoors or in a well-ventilated area.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
P304 + P340 + P312 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 : Store in a well-ventilated place. Keep cool.
P405 : Store locked up.
Related Laws:
Transport Information:
UN Number UN1993
Class 3
Packing Group II
H.S.code* 2903.69-000
*This code is applied to the products when TCI exports from Japan and not for import in your country.
Application
Enamide synthesis via cross-coupling

Application: To a screw-cap vial are added 1 (1.0 eq.),  vinyl bromide (1.0 M soln. in THF, 2.0 eq.), CuI (0.05 eq.), N,N’-dimethylethylenediamine (0.10 eq.), and K2CO3 (2.0 eq.). The vial is tightly sealed and heated to 80 °C to stir overnight. Upon completion of the reaction, the mixture is filtered through a pad of celite, rinsing with EtOAc, and solvent is removed in vacuo to afford a crude product. Purification of the resulting crude residue via silica gel flash chromatography (gradient elution: EtOAc in n-hexanes) affords 2 (58% yield) as a yellow solid.

References


PubMed Literature

Please visit the Pubchem page at this link.

Articles/Brochures

TCIMAIL
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.

The requested SDS is not available.

Please Contact Us for more information.

Specifications
C of A & Other Certificates
Please enter Lot Number Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.

The product with the lot number searched for has been discontinued and no related documentation is available.

Sample C of A
This is a sample C of A and may not represent a recently manufactured lot of the product.

A sample C of A for this product is not available at this time.

Analytical Charts
Please enter Lot Number Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.

The requested analytical chart is not available. Sorry for the inconvenience.

The product with the lot number searched for has been discontinued and no related documentation is available.

Other Documents

Session Status
Your session will timeout in 10 minutes. You will be redirected to the HOME page after session timeout. Please click the button to continue session from the same page. minute. You will be redirected to the HOME page after session timeout. Please click the button to continue session from the same page.

Your session has timed out. You will be redirected to the HOME page.