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CAS RN: 5718-75-2 | Product Number: T2578
(1R,4R,5R)-4,7,7-Trimethyl-6-thiabicyclo[3.2.1]octane
Purity: >94.0%(GC)
Synonyms:
- (-)-Isothiocineole
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Product Number | T2578 |
Purity / Analysis Method | >94.0%(GC) |
Molecular Formula / Molecular Weight | C__1__0H__1__8S = 170.31 |
Physical State (20 deg.C) | Liquid |
Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
CAS RN | 5718-75-2 |
Reaxys Registry Number | 80225 |
PubChem Substance ID | 125307478 |
Specifications
Appearance | Colorless to Almost colorless clear liquid |
Purity(GC) | min. 94.0 % |
Optical purity(GC) | min. 98.0 ee% |
Properties (reference)
Boiling Point | 84 °C/5 mmHg |
Flash point | 79 °C |
Specific Gravity (20/20) | 1.00 |
Specific Rotation | -70° (C=1.32,CHCl3) |
Refractive Index | 1.52 |
GHS
Signal Word | Warning |
Hazard Statements | H227 : Combustible liquid. |
Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P280 : Wear protective gloves/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P403 + P235 : Store in a well-ventilated place. Keep cool. |
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Transport Information:
H.S.code* | 2934.99-000 |
Application
Chiral Sulfides for Optically Active Three-membered Rings
References
- 1) Practical and Highly Selective Sulfur Ylide Mediated Asymmetric Epoxidations and Aziridinations Using an Inexpensive, Readily Available Chiral Sulfide. Applications to the Synthesis of Quinine and Quinidine
- 2) Asymmetric synthesis of cyclopropyl phosphonates using chiral terpenyl sulfonium and selenonium ylidesw
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