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CAS RN: 3094-87-9 | Product Number: I0765
Iron(II) Acetate
Purity: >90.0%(T)
Synonyms:
- Acetic Acid Iron(II) Salt
Product Documents:
Size | Unit Price | Same Day | 2-3 Business Days |
---|---|---|---|
5G |
$72.00
|
20 | ≥100 |
25G |
$211.00
|
8 | ≥100 |
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Product Number | I0765 |
Purity / Analysis Method | >90.0%(T) |
Molecular Formula / Molecular Weight | C__4H__6O__4Fe = 173.93 |
Physical State (20 deg.C) | Solid |
Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
Store Under Inert Gas | Store under inert gas |
Condition to Avoid | Air Sensitive |
CAS RN | 3094-87-9 |
Reaxys Registry Number | 3996045 |
PubChem Substance ID | 125307293 |
MDL Number | MFCD00058909 |
Specifications
Appearance | White to Gray to Brown powder to crystal |
Purity(Potassium permanganate method) | min. 90.0 % |
Properties (reference)
GHS
Pictogram | |
Signal Word | Warning |
Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
Related Laws:
RTECS# | AI3850000 |
Transport Information:
H.S.code* | 2915.29-000 |
Application
Iron-catalyzed direct arylation
Typical procedure: To a dried vessel under argon atmosphere, the Fe(OAc)2 (4.5 mg), bathophenanthroline (16.6 mg), crushed dry KOtBu (112 mg), iodobenzene (102 mg) and benzene (3.9 g) were added. The reaction was stirred at room temperature for 20 min and then at 80 °C for 20 h. After cooling a mixture of CH2Cl2 / hexane (1:1) (2 mL) was added, and the solution was filtered through a silica pad. The pad was then rinsed with CH2Cl2 / hexane (1:1) (15 mL). The combined solutions were concentrated and the crude mixture was purified by column chromatography (eluent: hexanes) to give biphenyl as a white solid (75 mg, 89 %).
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