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CAS RN: 593-60-2 | Product Number: V0127
Vinyl Bromide (ca. 12% in Tetrahydrofuran, ca. 1.0mol/L)
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Purity:
Synonyms:
- Bromoethylene (ca. 12% in Tetrahydrofuran, ca. 1.0mol/L)
Product Documents:
| Size | Unit Price | Same Day | 2-3 Business Days | Other Lead Time |
Shipping Information
|
|---|---|---|---|---|---|
| 100ML |
₩198,000
|
4 | ≥100 | Contact Us |
* Please contact our distributor of SEJIN CI Co., Ltd.
if you would like to purchase TCI products. The above prices do not include freight cost, customs charge and other charges to the destination. SEJIN CI Co., Ltd. (Phone: 02-2655-2480 / email:
sales@sejinci.co.kr)
* The storage conditions are subject to change without notice.
* The storage conditions are subject to change without notice.
Supplemental Product Information:
100mL bottle of this product is attached with a DualSeal (Septum-type Bottle Cap).
For details, please refer to the page "DualSeal (Septum-type Bottle Cap)".
| Product Number | V0127 |
| Molecular Formula / Molecular Weight | C__2H__3Br = 106.95 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature | Refrigerated (0-10°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Light Sensitive,Air Sensitive,Heat Sensitive |
| Packaging and Container | 100ML-DualSeal Bottle (View image) |
| CAS RN | 593-60-2 |
| Reaxys Registry Number | 1361370 |
| PubChem Substance ID | 253661892 |
| MDL Number | MFCD00000183 |
Specifications
| Appearance | Colorless to Almost colorless clear liquid |
| Concentration(HNMR) | 11.5 to 12.5 w/w% |
| NMR | confirm to structure |
Properties (reference)
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H302 : Harmful if swallowed. H315 : Causes skin irritation. H319 : Causes serious eye irritation. H371 : May cause damage to organs. H372 : Causes damage to organs through prolonged or repeated exposure. H341 : Suspected of causing genetic defects. H350 : May cause cancer. H335 : May cause respiratory irritation. H225 : Highly flammable liquid and vapor. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P202 : Do not handle until all safety precautions have been read and understood. P240 : Ground/bond container and receiving equipment. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 : Keep container tightly closed. P201 : Obtain special instructions before use. P243 : Take precautionary measures against static discharge. P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 : Use only non-sparking tools. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor. P362 + P364 : Take off contaminated clothing and wash it before reuse. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. P304 + P340 + P312 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. P403 + P235 : Store in a well-ventilated place. Keep cool. P405 : Store locked up. |
Related Laws:
Transport Information:
| UN Number | UN1993 |
| Class | 3 |
| Packing Group | II |
| H.S.code* | 2903.69-000 |
Application
Enamide synthesis via cross-coupling
Application: To a screw-cap vial are added 1 (1.0 eq.), vinyl bromide (1.0 M soln. in THF, 2.0 eq.), CuI (0.05 eq.), N,N’-dimethylethylenediamine (0.10 eq.), and K2CO3 (2.0 eq.). The vial is tightly sealed and heated to 80 °C to stir overnight. Upon completion of the reaction, the mixture is filtered through a pad of celite, rinsing with EtOAc, and solvent is removed in vacuo to afford a crude product. Purification of the resulting crude residue via silica gel flash chromatography (gradient elution: EtOAc in n-hexanes) affords 2 (58% yield) as a yellow solid.
References
- Enamide-Benzyne-[2 + 2] Cycloaddition: Stereoselective Tandem [2 + 2] – Pericyclic Ring-Opening – Intramolecular N-Tethered [4 + 2] Cycloadditions
PubMed Literature
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Articles/Brochures
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Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
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Specifications
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Other Documents
Related Products
Vinyl Bromide (ca. 14% in Ethyl Ether, ca. 1.0mol/L)
| Product # | V0126 |
| CAS RN | 593-60-2 |
| Purity / Analysis Method: |