Published TCIMAIL newest issue No.197 | New tool "TCI SpectraViewer" | [Product Highlights] o-Nitrobenzyl Photolabile... | Product Document Searching Made Easy by 2D Code!
Maximum quantity allowed is 999
Please select the quantity
CAS RN: 557-20-0 | Product Number: D3214
Diethylzinc (ca. 15% in Hexane, ca. 1mol/L)
×
![]()
×
Purity:
Synonyms:
Product Documents:
| Size | Unit Price | Hyderabad | Japan* | Quantity |
|---|---|---|---|---|
| 100ML |
₹12,700.00
|
Contact Us | ≥100 |
|
| 500ML |
₹23,600.00
|
12 | ≥100 |
|
*Upon orders receipt, Hyderabad stocks will be dispatched on the same day.
*Items available in Japan warehouse will be dispatched in 10-12 working days.
*INR price is exclusive of domestic taxes applicable.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
Supplemental Product Information:
Both 100mL and 500mL bottles of this product are attached with a DualSeal (Septum-type Bottle Cap).
For details, please refer to the page "DualSeal (Septum-type Bottle Cap)".
| Product Number | D3214 |
| Molecular Formula / Molecular Weight | C__4H__1__0Zn = 123.50 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Moisture Sensitive |
| Packaging and Container | 100ML-DualSeal Bottle (View image), 500ML-DualSeal Bottle (View image) |
| CAS RN | 557-20-0 |
| Reaxys Registry Number | 3587207 |
| PubChem Substance ID | 87558704 |
| Merck Index (14) | 3131 |
| MDL Number | MFCD00009021 |
Specifications
| Appearance | Colorless to Light gray clear liquid to cloudy liquid |
| Concentration(HNMR) | 15.0 to 19.0 w/w% |
| NMR | confirm to structure |
Properties (reference)
| Specific Gravity (20/20) | 0.73 |
| Refractive Index | 1.50 |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H314 : Causes severe skin burns and eye damage. H361 : Suspected of damaging fertility or the unborn child. H372 : Causes damage to organs through prolonged or repeated exposure. H335 : May cause respiratory irritation. H336 : May cause drowsiness or dizziness. H304 : May be fatal if swallowed and enters airways. H401 : Toxic to aquatic life. H225 : Highly flammable liquid and vapor. H260 : In contact with water releases flammable gases which may ignite spontaneously. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P223 : Do not allow contact with water. P273 : Avoid release to the environment. P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P202 : Do not handle until all safety precautions have been read and understood. P240 : Ground/bond container and receiving equipment. P231 + P232 : Handle under inert gas. Protect from moisture. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 : Keep container tightly closed. P201 : Obtain special instructions before use. P243 : Take precautionary measures against static discharge. P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 : Use only non-sparking tools. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P335 + P334 : Brush off loose particles from skin. Immerse in cool water/ wrap in wet bandages. P308 + P313 : IF exposed or concerned: Get medical advice/ attention. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P310 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 : Wash contaminated clothing before reuse. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. P402 + P404 : Store in a dry place. Store in a closed container. P403 + P235 : Store in a well-ventilated place. Keep cool. P405 : Store locked up. |
Related Laws:
Transport Information:
| UN Number | UN3399 |
| Class | 4.3 / 3 |
| Packing Group | I |
Application
TCI Practical Example: Cross-Coupling Reaction Using the Perfluoroalkyl Zinc Reagent
-
Used Chemicals
-
Procedure
-
To a solution of diethylzinc (ca. 1mol/L in hexane, 2.9 mL, 2.9 mmol) and tridecafluorohexyl iodide (0.92 mL, 4.2 mmol) in DMPU (1.2 mL) was added ethyl 2-Iodobenzoate (500 mg, 1.9 mmol) and copper(I) iodide (37 mg, 0.20 mmol) and the reaction mixture was stirred under nitrogen at 90 °C for 16 hours. The reaction was quenched with 4 mol/L HCl and extracted with diethyl ether. The organic phase was dried over anhydrous sodium sulfate and filtered. The solvent was removed under reduced pressure and the residue was purified by column chromatography (on silica gel, hexane:dichloromethane = 7:1) to give 1 as a colorless oil (804 mg, 92% yield).
-
Experimenter’s Comments
-
The reaction mixture was monitored by NMR.
-
Analytical Data
-
Ethyl 2-(1,1,2,2,3,3,4,4,5,5,6,6,6-Tridecafluorohexyl)benzoate (1)
1H NMR (270 MHz, CDCl3); δ 7.67-7.57 (m, 4H), 4.38 (q, J = 7.0 Hz, 2H), 1.35 (t, J = 7.0 Hz, 3H)
-
Lead Reference
-
- Dialkylzinc-Mediated Cross-Coupling Reactions of Perfluoroalkyl and Perfluoroaryl Halides with Aryl Halides
PubMed Literature
Please visit the Pubchem page at this link.
Articles/Brochures
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.
The requested SDS is not available.
Please Contact Us for more information.
Specifications
C of A & Other Certificates
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
Sample C of A
This is a sample C of A and may not represent a recently manufactured lot of the product.
A sample C of A for this product is not available at this time.
Analytical Charts
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
The requested analytical chart is not available. Sorry for the inconvenience.
Other Documents
Related Products
Diethylzinc (ca. 15% in Toluene, ca. 1mol/L)
| Product # | D3902 |
| CAS RN | 557-20-0 |
| Purity / Analysis Method: |