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CAS RN: 88335-93-7 | Product Number: H1652
2-Hydrogen 1-Methyl (1S,2R)-1,2,3,6-Tetrahydrophthalate
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Purity: >98.0%(GC)(T)
Synonyms:
- (1S,2R)-1,2,3,6-Tetrahydrophthalic Acid 2-Hydrogen 1-Methyl Ester
- (1R,6S)-6-(Methoxycarbonyl)cyclohex-3-enecarboxylic Acid
Product Documents:
| Size | Unit Price | Same Day | 2-3 Business Days | Other Lead Time |
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| 500MG |
$168.00
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1 | 2 | Contact Us |
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| Product Number | H1652 |
| Purity / Analysis Method | >98.0%(GC)(T) |
| Molecular Formula / Molecular Weight | C__9H__1__2O__4 = 184.19 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| CAS RN | 88335-93-7 |
| PubChem Substance ID | 354334819 |
| MDL Number | MFCD00075490 |
Specifications
| Appearance | White to Light yellow powder to crystal |
| Purity(GC) | min. 98.0 % |
| Purity(Neutralization titration) | min. 98.0 % |
| Melting point | 64.0 to 68.0 °C |
| NMR | confirm to structure |
Properties (reference)
| Melting Point | 66 °C |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
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Transport Information:
| H.S.code* | 2917.20-000 |
Application
A Valuable Intermediate for the Synthesis of Biological Active Compounds
This product is a valuable intermediate for the synthesis of many biological active compounds, e.g. anticapsin, (+)-aucantene, cis-carbapenems.1,2) Furthermore, it is used for the synthesis of the tricyclic core of platencin (an antibiotic to MRSA), DC-SIGN (useful for the treatment of HIV infection), alstoscholarine (a traditional medicine in South and Southeast Asia) and Brefeldin A (a macrolide antibiotic).3-6)
References
- 1)Scale-Up of a Recombinant Pig Liver Esterase-Catalyzed Desymmetrization of Dimethyl Cyclohex-4-ene-cis-1,2-dicarboxylate
- 2)Enantioselective Syntheses and Absolute Configurations of Viridiene and Aucantene, Two Constitutents of Algae Pheromone Bouquets
- 3)Concise Synthesis of the Tricyclic Core of Platencin
- 4)Second generation of fucose-based DC-SIGN ligands: affinity improvement and specificity versus Langerin
- 5)Protecting-Group-Free Total Synthesis of (E)- and (Z)-Alstoscholarine
- 6)trans-Hydrogenation: Application to a Concise and Scalable Synthesis of Brefeldin A
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