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CAS RN: 1868173-15-2 | Product Number: T3622

[(4-Trifluoromethyl)phenyl](2,4,6-trimethoxyphenyl)iodonium p-Toluenesulfonate

Purity: >95.0%(HPLC)(qNMR)

Synonyms:

[(4-Trifluoromethyl)phenyl](2,4,6-trimethoxyphenyl)iodonium Tosylate

Product Documents:

Size	Unit Price	Shanghai	Tianjin	Japan*
200MG	¥115.00	Contact Us	Contact Us	5
1G	¥490.00	Contact Us	Contact Us	18

* For order or inquiry, please contact Our Authorized Distributors.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
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Supplemental Product Information:

This product is commercialized in partnership with Dr. Stuart and PSU.

General Information plus

Product Number	T3622
Purity / Analysis Method	>95.0%(HPLC)(qNMR)
Molecular Formula / Molecular Weight	C₂₃H₂₂F₃IO₆S = 610.38
Physical State (20 deg.C)	Solid
Storage Temperature	Refrigerated (0-10°C)
Condition to Avoid	Light Sensitive,Heat Sensitive
CAS RN	1868173-15-2
Reaxys Registry Number	29449543
PubChem Substance ID	354334572

Specifications & Documents plus

Safety & Properties plus

Applications & Literature plus

Application

Asymmetric Diaryliodonium Tosylates Useful for Metal-free Arylations

P2412,T3622,D5145,B5269,T1110,F1111, B5573

References

1)Aryl(2,4,6-trimethoxyphenyl)iodonium Salts as Reagents for Metal-Free Arylation of Carbon and Heteroatom Nucleophiles
- D. R. Stuart, TCIMAIL 2017, 173, 3.
2)Unsymmetrical Aryl(2,4,6-trimethoxyphenyl)iodonium Salts: One-Pot Synthesis, Scope, Stability, and Synthetic Studies
- T. L. Seidl, S. K. Sundalam, B. McCullough, D. R. Stuart, J. Org. Chem. 2016, 81, 1998.
3)Single-step syntheses of no-carrier-added functionalized [¹⁸F]fluoroarenes as labeling synthons from diaryliodonium salts
- J. Chun, V. W. Pike, Org. Biomol. Chem. 2013, 6300.

Application

Hypervalent iodine compounds usable for arylating reactions

Stuart et al. have designed and synthesized some diaryl-substituted hypervalent iodine compounds having a 1,3,5-trimethoxybenzene (TMB) moiety and an aromatic ring. In these compounds, the TMB moiety acts as a leaving group so that the other aromatic ring can be used for the aryl group introduction. Various functional groups such as cyano, nitro, fluoro, or chloro substituted aromatic TMB hypervalent iodine compounds have been reported so far. It is expected to use these compounds for transition-metal-free arylations.

References

Unsymmetrical Aryl(2,4,6-trimethoxyphenyl)iodonium Salts: One-Pot Synthesis, Scope, Stability, and Synthetic Studies
- T. L. Seidl, S. K. Sundalam, B. McCullough, D. R. Stuart, J. Org. Chem. 2016, 81, 1998.

PubMed Literature

Articles/Brochures

Hypervalent Iodine Compounds

TCIMAIL

[Product Highlights] Asymmetric Diaryliodonium Tosylates Useful for Metal-free Arylations

Product Documents (Note: Some products will not have analytical charts available.)

Safety Data Sheet (SDS)

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Specifications

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Analytical Charts

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Appearance	White to Light yellow powder to crystal
Purity(HPLC)	min. 95.0 %(excluding counter anion)
Purity(qNMR)	min. 95.0 %
NMR	confirm to structure

Pictogram
Signal Word	Warning
Hazard Statements	H315 : Causes skin irritation. H319 : Causes serious eye irritation.
Precautionary Statements	P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention.

CAS RN: 1868173-15-2 | Product Number: T3622

[(4-Trifluoromethyl)phenyl](2,4,6-trimethoxyphenyl)iodonium p-Toluenesulfonate

References

References

Articles/Brochures

Safety Data Sheet (SDS)

Specifications

C of A & Other Certificates

Sample C of A

Analytical Charts

Other Documents

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