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CAS RN: 492-08-0 | Product Number: S0884
(+)-Sparteine
Purity: >98.0%(GC)
Synonyms:
- Pachycarpine
Product Documents:
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1G |
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Product Number | S0884 |
Purity / Analysis Method | >98.0%(GC) |
Molecular Formula / Molecular Weight | C__1__5H__2__6N__2 = 234.39 |
Physical State (20 deg.C) | Liquid |
Storage Temperature | Refrigerated (0-10°C) |
Store Under Inert Gas | Store under inert gas |
Condition to Avoid | Air Sensitive,Heat Sensitive |
CAS RN | 492-08-0 |
Reaxys Registry Number | 82448 |
PubChem Substance ID | 160871001 |
MDL Number | MFCD00869353 |
Specifications
Appearance | Colorless to Light orange to Yellow clear liquid |
Purity(GC) | min. 98.0 % |
Optical purity(GC) | min. 99.0 ee% |
NMR | confirm to structure |
Properties (reference)
Boiling Point | 174 °C/8 mmHg |
Flash point | 148 °C |
Specific Rotation | 18° (C=1,EtOH) |
Refractive Index | 1.53 |
Maximum Absorption Wavelength | 202(CH3CN) nm |
Solubility (slightly sol. in) | Ethanol |
GHS
Pictogram | |
Signal Word | Warning |
Hazard Statements | H302 : Harmful if swallowed. H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P270 : Do not eat, drink or smoke when using this product. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. |
Related Laws:
RTECS# | RT0620000 |
Transport Information:
H.S.code* | 2939.79-000 |
Application
Sparteines as Chiral Ligands for Asymmetric Synthesis
References
- 1)Review of (?)-sparteine as a chiral ligand for metal catalysts
- 2)Review of enantioselective synthesis with Li/(?)-sparteine carbanion pairs
- 3)Asymmetric lithiation of (?)-sparteine and (+)-sparteine
- 4)Asymmetric aldol additions using (?)-sparteine and TiCl4
- 5)Palladium-catalyzed oxidative kinetic resolutions of secondary alcohols with (?)-sparteine
- 6)Enantiomer-selective polymerizations using (?)-sparteine
Application
Total Synthesis of (+)-Sparteine
References
- First Asymmetric Total Synthesis of (+)-Sparteine
- Asymmetric total synthesis of (+)-sparteine and the synthesis of a readily accessible (+)-sparteine surrogate
- R. Iyengar, V. Gracias, Chemtracts 2004, 17, 92.
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