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CAS RN: 14592-56-4 | Product Number: B1676

Bis(acetonitrile)palladium(II) Dichloride


Purity: >98.0%(T)
Synonyms:
  • Dichlorobis(acetonitrile)palladium(II)
Product Documents:
1G
A$228.00
≥60  ≥80 
5G
A$722.00
26   14  
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Product Number B1676
Purity / Analysis Method >98.0%(T)
Molecular Formula / Molecular Weight C__4H__6Cl__2N__2Pd = 259.43 
Physical State (20 deg.C) Solid
Storage Temperature Room Temperature (Recommended in a cool and dark place, <15°C)
Packaging and Container 1G-Glass Bottle with Plastic Insert (View image)
CAS RN 14592-56-4
Reaxys Registry Number 14640205
PubChem Substance ID 87564577
SDBS (AIST Spectral DB) 17192
MDL Number

MFCD00013122

Specifications
Appearance Light yellow to Brown powder to crystaline
Purity(Chelometric Titration) min. 98.0 %
Properties (reference)
GHS
Pictogram Pictogram
Signal Word Danger
Hazard Statements H301 + H311 + H331 : Toxic if swallowed, in contact with skin or if inhaled.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P261 : Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P270 : Do not eat, drink or smoke when using this product.
P271 : Use only outdoors or in a well-ventilated area.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing.
P361 + P364 : Take off immediately all contaminated clothing and wash it before reuse.
P301 + P310 + P330 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth.
P302 + P352 + P312 : IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/doctor if you feel unwell.
P304 + P340 + P311 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor.
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
P405 : Store locked up.
Related Laws:
Transport Information:
UN Number UN3439
Class 6.1
Packing Group III
H.S.code* 2843.90-000
*This code is applied to the products when TCI exports from Japan and not for import in your country.
Application
Synthesis of Oxindoles

Typical Procedure: To a dried screw-cap vial is added anilide (0.3 mmol), AgOCOCF3 (132.5 mg, 0.6 mmol), (CH3CN)2PdCl2 (3.5 mg, 0.015 mmol) and chlorobenzene. The reaction mixture is stirred at 100-120 °C for 3-12 h in a pre-heated oil bath. After cooling to room temperature, the reaction is diluted with EtOAc and filtered with a glass filter. The filtrate is washed with 5% aqueous NaHCO3 and brine. The extract is dried over MgSO4 and concentrated in vacuo. The crude is purified by preparative TLC.

References


PubMed Literature


Product Documents (Note: Some products will not have analytical charts available.)
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