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Fluorous Ether Solvents

Heptafluoropropyl Methyl Ether (Product No. H1773), Methyl Nonafluorobutyl Ether (mixture of isomers) (Product No. M1345), Ethyl Nonafluorobutyl Ether (mixture of isomers) (Product No. E0528) and 1,1,1,2,2,3,4,5,5,5-Decafluoro-3-methoxy-4-(trifluoromethyl)pentane (Product No. D4484) are hydrofluoroethers, also known as HFE-7000, HFE-7100, HFE-7200, and HFE-7300, respectively.1) These hydrofluoroethers are not only used as solvents and diluents,2,3) but their use as refrigerants,4) heat transfer fluids,5) cleaning agents,6) and electrolytic solvents7) has also been reported.

Heptafluoropropyl Methyl Ether (= HFE-7000)
Methyl Nonafluorobutyl Ether (mixture of isomers) (= HFE-7100)
Ethyl Nonafluorobutyl Ether (mixture of isomers) (= HFE-7200)
1,1,1,2,2,3,4,5,5,5-Decafluoro-3-methoxy-4-(trifluoromethyl)pentane (= HFE-7300)

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Advantages 8,9)

  • HFE-7000: melting point 34°C; freezing point -123°C; specific gravity 1.42
  • HFE-7001: melting point 61°C; freezing point -135°C; specific gravity 1.53
  • HFE-7002: melting point 76°C; freezing point -138°C; specific gravity 1.44
  • HFE-7003: melting point 100°C; freezing point -38°C; specific gravity 1.67

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References

  1. 1) Protection of Stratospheric Ozone: Notice 16 for Significant New Alternatives Policy Program
  2. 2) Highly fluorinated organic–inorganic nanocomposites with improved refractive index and photopatterning properties
  3. 3) Transparent fluids for 157-nm immersion lithography
  4. 4) The potential of hydrofluoroethers to replace CFCs, HCFCs and PFCs
  5. 5) Performance analysis of the different Organic Rankine Cycles (ORCs) using dry fluids
  6. 6) Estimation of the suitability of selected organic solvents for ultrasonic cleaning
  7. 7) A Multi-Functional Electrolyte for Lithium-Ion Batteries
  8. 8) Density, Surface Tension, and Kinematic Viscosity of Hydrofluoroethers HFE-7000, HFE-7100, HFE-7200, HFE-7300, and HFE-7500
  9. 9) Critical Properties of Fluorinated Ethers

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