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CAS RN: 2613-27-6 | Product Number: N0743
4-Nitrophenylsulfur Pentafluoride
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Purity: >96.0%(GC)
Synonyms:
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 1G |
$20.00
|
2 | 1 | Contact Us |
|
| 5G |
$45.00
|
Contact Us | Contact Us | Contact Us |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
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Specifications
| Appearance | White or Colorless to Yellow powder to lump to clear liquid |
| Purity(GC) | min. 96.0 % |
| Melting point | 37.0 to 41.0 °C |
Properties (reference)
| Melting Point | 39 °C |
| Boiling Point | 77 °C/12 mmHg |
| Refractive Index | 1.47 |
| Solubility in water | Insoluble |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H301 + H311 + H331 : Toxic if swallowed, in contact with skin or if inhaled. H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P261 : Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P362 : Take off contaminated clothing and wash before reuse. P301 + P310 + P330 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth. P302 + P352 + P312 : IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/doctor if you feel unwell. P304 + P340 + P311 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. P405 : Store locked up. |
Related Laws:
Transport Information:
| UN Number (DOT-AIR) | UN2811 |
| Class (DOT-AIR) | 6.1 |
| Packing Group (TCI-A) | III |
| HS Number | 2930.90.2900 |
Application
4-ニトロフェニルサルファーペンタフルオリドの位置選択的アリール化反応
A 25 mL Schlenk tube equipped with a magnetic stir bar is charged with (allylPdCl)2 (2.5 mol%), PCy3·HBF4 (7.5 mol%), and K2CO3 (1.8 equiv.). The reaction tube is evacuated and bakfilled with N2 (4 times), then 2,2-dimethylbutyric acid (0.3 equiv.), bromobenzene (2.5 equiv.), toluene (1.0 mL) and 4-nitrophenylsulfur pentafluoride (0.3 mmol, 1.0 equiv.) are added subsequently. The sealed tube is screw capped and heated to 130 °C for 15h. The reaction vessel is then cooled to room temperature, and the reaction mixture is concentrated in vacuo directly. The resulting residue is purified with silica gel chromatography to afford 2'-nitro-[1,1':3',1''-terphenyl]-5'-yl sulfurpentafluoride in 87% yield.
References
- Pd-Catalyzed Direct Arylation of Nitro(pentafluorosulfanyl)benzenes with Aryl Bromides
PubMed Literature
Articles/Brochures
TCIMAIL
[TCIMAIL No.158] Pentafluorosulfanyl Compounds[Research Articles] Arylations of nitro(pentafluorosulfanyl)benzenes using a palladium catalyst
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
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Specifications
C of A & Other Certificates
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