Make sure to sign up for an account today for exclusive coupons and free shipping on orders over $75!
Maximum quantity allowed is 999
Please select the quantity
CAS RN: 106294-60-4 | Product Number: B4893
(2,2'-Bipyridine)bis(2-phenylpyridinato)iridium(III) Hexafluorophosphate
×
![]()
×
Purity: >90.0%(HPLC)
Synonyms:
- [Ir(ppy)2(bpy)]PF6
- (2,2'-Bipyridine-κN1,κN1')bis[2-(2-pyridinyl-κN)phenyl-κC]iridium(III) Hexafluorophosphate
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 200MG |
$307.00
|
1 | 2 | 19 |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
* To send your quote request for bulk quantities, please click on the "Request Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | B4893 |
| Purity / Analysis Method | >90.0%(HPLC) |
| Molecular Formula / Molecular Weight | C__3__2H__2__4F__6IrN__4P = 801.75 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| CAS RN | 106294-60-4 |
| Reaxys Registry Number | 16526752 |
| PubChem Substance ID | 253661417 |
Specifications
| Appearance | Light yellow to Brown powder to crystal |
| Purity(HPLC) | min. 90.0 area% |
| Elemental analysis(Nitrogen) | 6.00 to 8.00 % |
Properties (reference)
| Melting Point | 250 °C |
| Maximum Absorption Wavelength | 255(CH3CN) nm |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302 + P352 : IF ON SKIN: Wash with plenty of soap and water. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P362 : Take off contaminated clothing and wash before reuse. |
Related Laws:
Transport Information:
| HS Number | 2843.90.0000 |
Application
TCI Practical Example: The Synthesis of α-Aminoamide Catalyzed by a Visible Light Photoredox Catalyst
-
Used Chemicals
-
Procedure
-
N,N-Dimethylaniline (0.18 g, 1.5 mmol, 1.0 eq), TosMIC (0.439g, 2.25 mmol, 1.5 eq), Ir[(ppy)2(bpy)]PF6 (12 mg, 0.015 mmol, 1.0 mol%), ion-exchanged water (0.27 mL, 15 mmol, 10 eq) were dissolved in acetonitrile (10 mL) at rt under N2. The mixture was placed at a distance of 2-3 cm from Blue LED lamp. The orange solution was stirred at rt under visible light irradiation. After 2 days of irradiation, the solvent was removed in vacuo and the resulting residue was purified by column chromatography on silica gel (hexane:ethyl acetate = 9:1 – 1:1 - 0:1) to give compound 1 as a light blown solid (131 mg, y. 26%).
-
Experimenter’s Comments
-
Acetonitrile was degassed with nitrogen for 1 hour before use.
Irradiation of visible light was performed with Kessil A160WE Tuna Blue 40W×2.
The reaction mixture was monitored by 1H NMR and TLC (hexane:ethyl acetate = 1:1, Rf = 0.23).
-
Analytical Data
-
Compound 1
1H NMR (400 MHz, CDCl3); δ 7.72 (d, J = 8.2 Hz, 2H), 7.34-7.27 (m, 5H), 6.89 (t, J = 6.9 Hz, 1H), 6.67 (d, J = 8.7 Hz, 2H), 4.69 (d, J = 6.9 Hz, 2H), 3.75 (s, 2H), 2.99 (s, 3H), 2.45 (s, 3H).
13C NMR (101 MHz, CDCl3); δ 170.3, 148.9, 145.6, 133.6, 129.9, 129.4, 128.8, 119.2, 113.3, 59.8, 58.5, 40.0, 21.8.
-
Lead Reference
-
- Visible Light Photoredox-Catalyzed Multicomponent Reactions
-
Other References
-
- (review) A Retrosynthetic Approach for Photocatalysis
PubMed Literature
Articles/Brochures
TCIMAIL
[TCIMAIL No.171] Visible Light Photoredox Catalysts[Product Highlights] Visible Light Photoredox Catalysts Useful for Chemical Modifications
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.
The requested SDS is not available.
Please Contact Us for more information.
Specifications
C of A & Other Certificates
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
Sample C of A
This is a sample C of A and may not represent a recently manufactured lot of the product.
A sample C of A for this product is not available at this time.
Analytical Charts
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
The requested analytical chart is not available. Sorry for the inconvenience.