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CAS RN: 14694-95-2 | Product Number: T0931

Tris(triphenylphosphine)rhodium(I) Chloride


Purity: >98.0%(T)
Synonyms:
  • Chlorotris(triphenylphosphine)rhodium(I)
  • Wilkinson Catalyst
Product Documents:
1G
$159.00
5   9   ≥100 

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Product Number T0931
Purity / Analysis Method >98.0%(T)
Molecular Formula / Molecular Weight C__5__4H__4__5ClP__3Rh = 925.23 
Physical State (20 deg.C) Solid
Storage Temperature Room Temperature (Recommended in a cool and dark place, <15°C)
Store Under Inert Gas Store under inert gas
Condition to Avoid Light Sensitive,Air Sensitive
Packaging and Container 1G-Glass Bottle with Plastic Insert (View image)
CAS RN 14694-95-2
Reaxys Registry Number 14664394
PubChem Substance ID 87576749
SDBS (AIST Spectral DB) 5193
Merck Index (14) 9758
MDL Number

MFCD00010016

Specifications
Appearance Orange to Brown to Dark red powder to crystal
Purity(Argentometric Titration) min. 98.0 %
NMR confirm to structure
Properties (reference)
Solubility in water Insoluble
Solubility (soluble in) Benzene, Toluene, dichloromethane, Chloroform
GHS
Pictogram Pictogram
Signal Word Warning
Hazard Statements H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
Precautionary Statements P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P302 + P352 : IF ON SKIN: Wash with plenty of soap and water.
P332 + P313 : If skin irritation occurs: Get medical advice/ attention.
P362 : Take off contaminated clothing and wash before reuse.
Related Laws:
Transport Information:
HS Number 2843.90.0000
Application
Trimethylsilylation of Alcohols using TMS Reagents

T0931

Reference

  • Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols
    • P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.


Application
Wilkinson’s Catalyst: a Homogeneous Catalyst for Hydrogenation

References


Application
Rh-catalyzed Coupling Reaction between THF and Olefins

Reference


PubMed Literature


TCIMAIL
Product Documents (Note: Some products will not have analytical charts available.)
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