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CAS RN: 12154-84-6 | Product Number: A2981
(Acetylacetonato)(1,5-cyclooctadiene)iridium(I)
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Purity:
Synonyms:
- Ir(acac)(COD)
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 200MG |
$122.00
|
4 | Contact Us | 25 |
|
| 1G |
$365.00
|
1 | Contact Us | 18 |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
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| Product Number | A2981 |
| Molecular Formula / Molecular Weight | C__1__3H__1__9IrO__2 = 399.51 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive |
| CAS RN | 12154-84-6 |
| Reaxys Registry Number | 14337429 |
| PubChem Substance ID | 354333737 |
| MDL Number | MFCD08273779 |
Specifications
| Appearance | Light yellow to Amber to Dark green powder to crystaline |
| Elemental analysis(Carbon) | 37.10 to 41.00 % |
Properties (reference)
| Melting Point | 155 °C |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302 + P352 : IF ON SKIN: Wash with plenty of soap and water. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P362 : Take off contaminated clothing and wash before reuse. |
Related Laws:
| RTECS# | NO3615000 |
Transport Information:
| HS Number | 2843.90.0000 |
Application
ortho-Selective C-H Silylation of Aryl Compounds Using an Iridium Catalyst
Experimental procedure (R = Ph)1):
A mixture of Ir(acac)(COD) (4.0 mg, 0.010 mmol), 2-phenylpyridine (31.0 mg, 0.200 mmol), fluorodiphenylsilane (56.6 mg, 0.280 mmol), and 2-norbornene (75.3 mg, 0.800 mmol) in toluene (1.0 mL) is stirred at 115 °C for 24 h. Upon completion of the reaction, the crude product is purified by column chromatography on silica gel (hexane:EtOAc = 9:1) to afford pure 1 as a white solid (66.2 mg, 93%).
A mixture of Ir(acac)(COD) (4.0 mg, 0.010 mmol), 2-phenylpyridine (31.0 mg, 0.200 mmol), fluorodiphenylsilane (56.6 mg, 0.280 mmol), and 2-norbornene (75.3 mg, 0.800 mmol) in toluene (1.0 mL) is stirred at 115 °C for 24 h. Upon completion of the reaction, the crude product is purified by column chromatography on silica gel (hexane:EtOAc = 9:1) to afford pure 1 as a white solid (66.2 mg, 93%).
References
- 1)Iridium-Catalyzed ortho-Selective C－H Silylation of Aromatic Compounds Directed toward the Synthesis of π‑Conjugated Molecules with Lewis Acid－Base Interaction
- 2)Palladium-Catalyzed C-H Fluorosilylation of 2-Phenylpyridines: Synthesis of Silafluorene Equivalents
PubMed Literature
Articles/Brochures
TCIMAIL
[Research Articles] ortho-Selective C-H Silylation of Aryl Compounds Using an Iridium CatalystProduct Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
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Specifications
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