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CAS RN: 1420299-84-8 | Product Number: C3328
Chloro[(1,2,3,4,5,6-η)-2,2'',4,4'',6,6''-hexamethyl[1,1':3',1''-terphenyl]-2'-thiolato-κS][tris(4-fluorophenyl)phosphine-κP]ruthenium(II)
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![Chloro[(1,2,3,4,5,6-η)-2,2'',4,4'',6,6''-hexamethyl[1,1':3',1''-terphenyl]-2'-thiolato-κS][tris(4-fluorophenyl)phosphine-κP]ruthenium(II)](/_ui/responsive/theme-tci/images/missing_product_zoom.jpg "Chloro[(1,2,3,4,5,6-η)-2,2'',4,4'',6,6''-hexamethyl[1,1':3',1''-terphenyl]-2'-thiolato-κS][tris(4-fluorophenyl)phosphine-κP]ruthenium(II)")
Purity:
Synonyms:
- [(DmpSR')RuCl(P-(4-Fluorophenyl)3)]
Product Documents:
| Size | Unit Price | Same Day | 2-3 Business Days | Other Lead Time |
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|---|---|---|---|---|---|
| 100MG |
$89.00
|
21 | 13 | Contact Us |
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| Product Number | C3328 |
| Molecular Formula / Molecular Weight | C__4__2H__3__7ClF__3PRuS = 798.31 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive |
| CAS RN | 1420299-84-8 |
| Reaxys Registry Number | 23375447 |
| PubChem Substance ID | 354334201 |
Specifications
| Appearance | Light yellow to Yellow to Orange powder to crystal |
| Elemental analysis(Carbon) | 60.50 to 65.50 % |
| Elemental analysis(Hydrogen) | 4.40 to 5.00 % |
| NMR | confirm to structure |
Properties (reference)
GHS
Related Laws:
Transport Information:
| H.S.code* | 2843.90-000 |
Application
Hydrodefluorination of Trifluoromethyl Group Using a Ruthenium Catalyst
Experimental procedure: A reaction tube is charged in a glovebox with a mixture of 1 (3.6 mg, 2.3 µmol) and CH3ONa (1.2 µmol). After addition of tetracosane (2.0 mg) as internal standard, n-hexane (0.5 mL) and diphenylmethylsilane (20 mg, 0.10 mmol) are added dropwise to the suspension. N,N-Diethyl-3-trifluoromethylaniline (5.0 mg, 23 µmol) is added, and the reaction mixture is maintained at ambient temperature for 6 h. Product formation is monitored by GLC and verified by GLC-MS.
References
- C(sp3)－F Bond Activation of CF3‑Substituted Anilines with Catalytically Generated Silicon Cations: Spectroscopic Evidence for a Hydride-Bridged Ru－S Dimer in the Catalytic Cycle
PubMed Literature
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