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Highly Regioselective Organic Semiconducting Polymer: P3HT
No.176(January 2018)
Poly(3-hexylthiophene) (P3HT, 1) is widely useful in organic electronics research fields, and is a representative material of soluble organic semiconducting polymers. The performance of electronic materials is typically dependent on the quality of the material. Among them, purity and molecular weight are important factors for the material performance. 1 was synthesized by a direct arylation polymerization (DArP)1,2) and features a highly regioselective structure with a consistent average molecular weight and polydispersity index. In addition, 1 is useful for solution process-able organic solar cells,3,4) perovskite solar cells,5) and organic transistor research,6) due in part to its high solubility.
Figure 1. Organic Photovoltaics (OPV)
Figure 2. Perovskite Solar Cell (PSC)
Figure 3. Organic Transistor (OFET)
This material was produced by collaboration with Prof. Fumiyuki Ozawa
at Institute for Chemical Research, Kyoto University.
References
- 1)Palladium-catalyzed dehydrohalogenative polycondensation of 2-bromo-3-hexylthiophene: An efficient approach to head-to-tail poly(3-hexylthiophene)
- 2)Structural analysis of poly(3-hexylthiophene) prepared via direct heteroarylation polymerization
- 3)A review of recent plasmonic nanoparticles incorporated P3HT: PCBM Organic thin film solar cells
- 4)Poly(3-hexylthiophene): Synthetic methodologies and properties in bulk heterojunction solar cells
- 5)Hole-transport materials for perovskite solar cells
- 6)25th Anniversary article: Organic field-effect transistors: The path beyond amorphous silicon
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