2,2'-Bipyridine Derivatives for the Synthesis of Covalent Organic Frameworks (COFs)

[2,2'-Bipyridine]-5,5'-dicarbaldehyde (1) and [2,2'-bipyridine]-5,5'-diamine (2) are bipyridine derivatives that can be used in the synthesis of covalent organic frameworks (COFs). COFs are crystalline porous materials with a wide range of promising applications such as catalysis, gas adsorption, and gas separation, due to their porosity and well-defined periodic structures. Additionally, functionalized COFs utilizing 1 or 2 have been developed by coordinating to metal atoms at bipyridine sites or quaternizing bipyridine sites using 1,2-dibromoethane. For instance, catalysts for the oxygen evolution reaction in water electrolysis,¹⁾ photocatalysts for the hydrogen evolution reaction,²⁾ and materials for photothermal conversion³⁾ have been reported.

Related Products

B6576

[2,2'-Bipyridine]-5,5'-dicarbaldehyde

D2893

[2,2'-Bipyridine]-5,5'-diamine

References

• 1) Regulating the Synergistic Effect in Bimetallic Two-Dimensional Polymer Oxygen Evolution Reaction Catalysts by Adjusting the Coupling Strength Between Metal Centers
  • D. Fa, J. Yuan, G. Feng, S. Lei, W. Hu, Angew. Chem. Int. Ed. 2023, 62, e202300532.
• 2) Integrating Light-Harvesting Ruthenium(II)-based Units into Three-Dimensional Metal Covalent Organic Frameworks for Photocatalytic Hydrogen Evolution
  • W.-K. Han, Y. Liu, X. Yan, Y. Jiang, J. Zhang, Z.-G. Gu, Angew. Chem. Int. Ed. 2022, 61, e202208791.
• 3) Stable Radical Cation-Containing Covalent Organic Frameworks Exhibiting Remarkable Structure-Enhanced Photothermal Conversion
  • Z. Mi, P. Yang, R. Wang, J. Unruangsri, W. Yang, C. Wang, J. Guo, J. Am. Chem. Soc. 2019, 141, 14433.

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