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CAS RN: 994-30-9 | 產品號碼: T0589
Chlorotriethylsilane
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| 產品號碼 | T0589 |
| 純度/分析方法 | >97.0%(GC) |
| 分子式 / 分子量 | C__6H__1__5ClSi = 150.72 |
| 外觀與形狀（20°C） | Liquid |
| 儲存條件 | Room Temperature (Recommended in a cool and dark place, <15°C) |
| 儲存在惰性氣體下 | Store under inert gas |
| 應避免的情況 | Moisture Sensitive |
| CAS RN | 994-30-9 |
| Reaxys-RN | 1732860 |
| PubChem Substance ID | 87576486 |
| SDBS (AIST Spectral DB) | 5610 |
| MDL編號 | MFCD00000507 |
產品規格
| Appearance | Colorless to Light yellow clear liquid |
| Purity(GC) | min. 97.0 % |
性質
| 沸點 | 149 °C |
| flp | 30 °C |
| 比重 | 0.90 |
| 折射率 | 1.43 |
GHS
| 圖形表示 |
|
| 信號詞 | Danger |
| 危險性說明 | H314 : Causes severe skin burns and eye damage. H226 : Flammable liquid and vapor. H290 : May be corrosive to metals. |
| 防範說明 | P501 : Dispose of contents/ container to an approved waste disposal plant. P240 : Ground/bond container and receiving equipment. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 : Keep container tightly closed. P234 : Keep only in original container. P243 : Take precautionary measures against static discharge. P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 : Use only non-sparking tools. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P390 : Absorb spillage to prevent material damage. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 : Wash contaminated clothing before reuse. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P403 + P235 : Store in a well-ventilated place. Keep cool. P406 : Store in corrosive resistant container with a resistant inner liner. P405 : Store locked up. |
相關法規
運輸資料
| UN編號 | UN2986 |
| 類別 | 8 / 3 |
| 包裝類別 | II |
| HS編碼* | 2931.90-000 |
Application
TCI Practical Example: Protection of a Secondary Alcohol by TESCl
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Used Chemicals
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Procedure
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To a solution of (±)-1-phenylethyl alcohol (0.242 mL, 2.0 mmol) in THF (4 mL, 0.5 mol/L) was added imidazole (204 mg, 3.0 mmol), then TESCl (0.402 mL, 2.4 mmol) was added dropwise and the mixture was stirred at room temperature for 2 hours. Water (10 mL), ethyl acetate (20 mL) was added to the reaction mixture to quench and was extracted with ethyl acetate (10 mL x 3). The combined organic layer was dried over sodium sulfate and filtered. The solvent was removed under reduced pressure and the residue was purified by column chromatography (ethyl acetate:hexane = 0:100 - 3:97 on silica gel) to give triethyl((±)-1-phenylethoxy)silane as a colorless liquid (373 mg, 79%).
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Experimenter’s Comments
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The reaction mixture was monitored by TLC (ethyl acetate:hexane = 1:20, Rf = 0.70).
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Analytical Data
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triethyl((±)-1-phenylethoxy)silane
1H NMR (270 MHz, CDCl3); δ 7.36-7.18 (m, 5H), 4.86 (q, 1H, J = 6.2 Hz), 1.42 (d, 1H, J = 6.2 Hz), 0.94-0.87 (m, 9H), 0.64-0.51 (m, 6H).
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Lead Reference
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- Synthetic Versatility of Lipases: Application for Si-O Bond Formation and Cleavage
考研文獻
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