Maximum quantity allowed is 999
请选择数量
CAS RN: 2613-27-6 | 產品號碼: N0743
4-Nitrophenylsulfur Pentafluoride
* 以上價格已含運費關稅等但一些需要海運以及乾冰運輸的產品除外,詳情請與
當地經銷商
洽詢。
* TCI會時常優化儲存條件,儲存溫度請以在線目錄為準，敬請留意。
產品規格
| Appearance | White or Colorless to Yellow powder to lump to clear liquid |
| Purity(GC) | min. 96.0 % |
| Melting point | 37.0 to 41.0 °C |
性質
| 熔點 | 39 °C |
| 沸點 | 77 °C/12 mmHg |
| 折射率 | 1.47 |
| 水溶性 | Insoluble |
GHS
| 圖形表示 |
|
| 信號詞 | Danger |
| 危險性說明 | H301 + H311 + H331 : Toxic if swallowed, in contact with skin or if inhaled. H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| 防範說明 | P501 : Dispose of contents/ container to an approved waste disposal plant. P261 : Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P361 + P364 : Take off immediately all contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P301 + P310 + P330 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth. P302 + P352 + P312 : IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/doctor if you feel unwell. P304 + P340 + P311 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. P405 : Store locked up. |
相關法規
運輸資料
| UN編號 | UN2811 |
| 類別 | 6.1 |
| 包裝類別 | III |
| HS編碼* | 2930.90-900 |
Application
4-ニトロフェニルサルファーペンタフルオリドの位置選択的アリール化反応
A 25 mL Schlenk tube equipped with a magnetic stir bar is charged with (allylPdCl)2 (2.5 mol%), PCy3·HBF4 (7.5 mol%), and K2CO3 (1.8 equiv.). The reaction tube is evacuated and bakfilled with N2 (4 times), then 2,2-dimethylbutyric acid (0.3 equiv.), bromobenzene (2.5 equiv.), toluene (1.0 mL) and 4-nitrophenylsulfur pentafluoride (0.3 mmol, 1.0 equiv.) are added subsequently. The sealed tube is screw capped and heated to 130 °C for 15h. The reaction vessel is then cooled to room temperature, and the reaction mixture is concentrated in vacuo directly. The resulting residue is purified with silica gel chromatography to afford 2'-nitro-[1,1':3',1''-terphenyl]-5'-yl sulfurpentafluoride in 87% yield.
References
- Pd-Catalyzed Direct Arylation of Nitro(pentafluorosulfanyl)benzenes with Aryl Bromides
考研文獻
文章/手冊
TCIMail
[TCIMAIL No.158] Pentafluorosulfanyl Compounds[Research Articles] Arylations of nitro(pentafluorosulfanyl)benzenes using a palladium catalyst
產品文件 （部分產品的分析圖譜無法提供，敬請諒解。）
SDS
請選擇語言。
請求的SDS不可用。
如需更多幫助，請聯繫我們 。
產品規格
檢驗報告(CoA)及其他文檔
請輸入批號
輸入的批號不正確
示例 CoA
可下載CoA示例。注：該示例可能非最新批次的CoA。
目前沒有該產品的 CoA 示例。
分析圖譜
請輸入批號
輸入的批號不正確
很抱歉，您搜索的分析圖譜無法提供。