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CAS RN: 29892-37-3 | 產品號碼: C2719
Chloro(dimethylsulfide)gold(I)
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| 包裝 | 價格 | 同一天 | 2-3个工作日 |
|---|---|---|---|
| 200MG |
NT$3,720
|
5 | 2 |
| 1G |
NT$11,160
|
聯繫我們 | ≥100 |
* 以上價格已含運費關稅等但一些需要海運以及乾冰運輸的產品除外,詳情請與
當地經銷商
洽詢。
* TCI會時常優化儲存條件,儲存溫度請以在線目錄為準，敬請留意。
| 產品號碼 | C2719 |
| 純度/分析方法 | >97.0%(T) |
| 分子式 / 分子量 | C__2H__6AuClS = 294.55 |
| 外觀與形狀（20°C） | Solid |
| 儲存條件 | Refrigerated (0-10°C) |
| 儲存在惰性氣體下 | Store under inert gas |
| 應避免的情況 | Light Sensitive,Air Sensitive,Heat Sensitive |
| 包裝和容器 | 1G-Glass Bottle with Plastic Insert （閲覽圖片）, 200MG-Glass Bottle with Plastic Insert （閲覽圖片） |
| CAS RN | 29892-37-3 |
| Reaxys-RN | 16499725 |
| PubChem Substance ID | 253660095 |
| MDL編號 | MFCD00192090 |
產品規格
| Appearance | White to Light yellow powder to crystal |
| Purity(Argentometric Titration) | min. 97.0 % |
性質
| 熔點 | 160 °C(dec.) |
GHS
| 圖形表示 |
|
| 信號詞 | Warning |
| 危險性說明 | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| 防範說明 | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
相關法規
運輸資料
| HS編碼* | 2930.90-900 |
Application
Preparation of Gold(I)-Phosphine complexes
In a 20 mL screw-top vial is dissolved (SMe)2AuCl (C2719, 1.0 equiv) in CH2Cl2, and the resulting solution is cooled in an ice bath. A solution of the desired phosphine (D4501, 0.5 equiv) in CH2Cl2 is added dropwise, and the resulting solution is allowed to warm to room temperature and stirred for two hours. After TLC indicats complete consumption of the starting material, the reaction solution is concentrated in vacuo to yield the desired gold(I) complexes.
References
Application
Preparation of Gold(I)-NHC complexes
Ag2O (0.5 mmol) is added to a solution of the imidazolium ligand (1.0 mmol) in CH2Cl2. The suspension becomes clear after stirring 3 h at room temperature. Then a solution of Me2SAuCl (C2719, 1.0 mmol) in CH2Cl2 is added dropwise. The reaction mixture is stirred for another 4 h. Then the solution is filtered through Celite and the solvent is partially evaporated. Addition of hexane leads to the precipitation of the methiodides.
References
考研文獻
產品文件 （部分產品的分析圖譜無法提供，敬請諒解。）