text.skipToContent text.skipToNavigation

Maximum quantity allowed is 999

Please select the quantity

CAS RN: 910110-45-1 | Product Number: H1407

(2S)-N-[(1S)-1-(Hydroxydiphenylmethyl)-3-methylbutyl]-2-pyrrolidinecarboxamide


Purity: >98.0%(T)(HPLC)
Synonyms:
  • (S)-N-[(S)-1-Hydroxy-4-methyl-1,1-diphenylpentan-2-yl]pyrrolidine-2-carboxamide
  • N-[(1S)-1-(Hydroxydiphenylmethyl)-3-methylbutyl]-L-prolinamide
  • Singh's Catalyst
Product Documents:
200MG
NT$3,960
6   1  
1G
NT$12,480
1   Contact Us

* The above prices include freight cost, customs, and other charges to the destination except for products that need to be shipped by sea or dry ice. For details, please contact our distributor in Taiwan to order our product.
* The storage conditions are subject to change without notice.


Product Number H1407
Purity / Analysis Method >98.0%(T)(HPLC)
Molecular Formula / Molecular Weight C__2__3H__3__0N__2O__2 = 366.51 
Physical State (20 deg.C) Solid
Storage Temperature Room Temperature (Recommended in a cool and dark place, <15°C)
CAS RN 910110-45-1
Reaxys Registry Number 10473304
PubChem Substance ID 253661520
MDL Number

MFCD22200506

Specifications
Appearance White to Almost white powder to crystal
Purity(HPLC) min. 98.0 area%
Purity(Nonaqueous Titration) min. 98.0 %
Melting point 191.0 to 195.0 °C
Specific rotation [a]20/D -46.0 to -49.0 deg(C=1, CHCl3)
NMR confirm to structure
Properties (reference)
Melting Point 193 °C
Specific Rotation -47° (C=1,CHCl3)
Solubility (soluble in) Methanol
GHS
Related Laws:
Transport Information:
H.S.code* 2933.99-000
*This code is applied to the products when TCI exports from Japan and not for import in your country.
Application
An Efficient Chiral Organocatalyst for the Cross-aldol Reaction of Aliphatic Ketones with Aldehydes

H1407

An aldehyde (0.5 mmol) is added to a mixture of ketone (2 mmol) and Singh's catalyst (0.5 mol %) in brine (0.5 mL) at -5 °C. The reaction mixture is stirred and the progress of the reaction is monitored by TLC. After reaction is over, the reaction mixture is diluted with EtOAc (10 mL). The organic layer is separated and dried over anhydrous Na2SO4. It is purified over silica gel by column chromatography to give the aldol product.

References


PubMed Literature


Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.

The requested SDS is not available.

Please Contact Us for more information.

Specifications
C of A & Other Certificates
Please enter Lot Number Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.

The product with the lot number searched for has been discontinued and no related documentation is available.

Sample C of A
This is a sample C of A and may not represent a recently manufactured lot of the product.

A sample C of A for this product is not available at this time.

Analytical Charts
Please enter Lot Number Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.

The requested analytical chart is not available. Sorry for the inconvenience.

The product with the lot number searched for has been discontinued and no related documentation is available.

Other Documents

Session Status
Your session will timeout in 10 minutes. You will be redirected to the HOME page after session timeout. Please click the button to continue session from the same page. minute. You will be redirected to the HOME page after session timeout. Please click the button to continue session from the same page.

Your session has timed out. You will be redirected to the HOME page.