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一种可用于扩展π-共轭体系的硼芴
Fukushima、Shoji及其合作者报道了9-氯-9-硼芴参与的包括炔烃插入(1,2-碳硼化)和氧化脱硼/Csp2–Csp2偶联的连续反应,并得到了π-共轭体系被扩展了的产物分子。该连续反应可以通过一锅法进行,也可用于构建多种π-共轭体系,在有机电子学方面有潜在的应用前景。
文献
- Boron-mediated sequential alkyne insertion and C–C coupling reactions affording extended π-conjugated molecules