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Published TCIMAIL newest issue No.197 | Notice of Discontinuing the Use of Password-Protected Compressed Files | Product Document Searching Made Easy by 2D Code! | TCI Life Science News December 2024 | [TCIPracticalExample] Reduction of Amide Group Using... | Various analytical charts can be searched on each product detail page and Product Document Search (The kinds of analytical charts differ by product)
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叔胺和含碳亲核试剂间的需氧光氧化碳-碳键的形成
Itoh等人报道了叔胺和含碳亲核试剂间的需氧光氧化碳-碳键的形成。结果显示，在分子氧和2-chloroanthraquinone催化剂存在下，2-芳基-1,2,3,4-四氢异喹啉能够和硝基烷烃等含碳亲核试剂发生反应形成碳-碳键，反应经历可见光光照驱动的自由基过程。这一反应由通用的日光灯提供可见光、以分子氧为终端氧化剂，并使用有机光催化剂，因此它有望成为一种环境友好的催化氧化方法。
