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CAS RN: 492-08-0 | 产品编码: S0884
(+)-Sparteine
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技术规格
| Appearance | Colorless to Light orange to Yellow clear liquid |
| Purity(GC) | min. 98.0 % |
| Optical purity(GC) | min. 99.0 ee% |
| NMR | confirm to structure |
物性（参考值）
| 沸点 | 174 °C/8 mmHg |
| 闪点 | 148 °C |
| 比旋光度 [α]D | 18° (C=1,EtOH) |
| 折射率 | 1.53 |
| 最大吸收波长 | 202(CH3CN) nm |
| 溶解性（微溶于） | 乙醇 |
GHS
| 象形图 |
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| 信号词 | Warning |
| 危险性说明 | H302 : Harmful if swallowed. H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| 防范说明 | P501 : Dispose of contents/ container to an approved waste disposal plant. P270 : Do not eat, drink or smoke when using this product. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. |
相关法规
| RTECS# | RT0620000 |
运输信息
| HS编码* | 2939.79-000 |
应用
Sparteines as Chiral Ligands for Asymmetric Synthesis
References
- 1)Review of (?)-sparteine as a chiral ligand for metal catalysts
- 2)Review of enantioselective synthesis with Li/(?)-sparteine carbanion pairs
- 3)Asymmetric lithiation of (?)-sparteine and (+)-sparteine
- 4)Asymmetric aldol additions using (?)-sparteine and TiCl4
- 5)Palladium-catalyzed oxidative kinetic resolutions of secondary alcohols with (?)-sparteine
- 6)Enantiomer-selective polymerizations using (?)-sparteine
应用
Total Synthesis of (+)-Sparteine
References
- First Asymmetric Total Synthesis of (+)-Sparteine
- Asymmetric total synthesis of (+)-sparteine and the synthesis of a readily accessible (+)-sparteine surrogate
- R. Iyengar, V. Gracias, Chemtracts 2004, 17, 92.
参考文献
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技术规格
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