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CAS RN: 130-95-0 | 产品编码: Q0028

Quinine


纯度/分析方法: >98.0%(T)
别名:
  • 奎宁
  • 金鸡纳碱
产品文档:
25G
S$180.00
13   ≥40  下单后约2周内可以发货
100G
S$498.00
4   18   下单后约2周内可以发货

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* TCI会时常优化储存条件,敬请留意。


产品编码 Q0028
纯度/分析方法 >98.0%(T)
分子式/分子量 C__2__0H__2__4N__2O__2 = 324.42 
外观与形状(20°C) 固体
储存温度 室温 (15°C以下阴凉干燥处)
储存在惰性气体下 存放于惰性气体之中
应避免的情况 光,湿气 (吸湿)
CAS RN 130-95-0
Reaxys-RN 5293630
PubChem物质ID 87575561
SDBS (AIST Spectral DB) 2170
Merck Index (14) 8061
MDL编号

MFCD00198096

技术规格
Appearance White to Almost white powder to crystal
Purity(HPLC) min. 96.0 area%
Purity(Nonaqueous Titration) min. 98.0 %
Melting point 174.0 to 179.0 °C
Specific rotation [a]20/D -160 to -170 deg(C=2, EtOH)
Solubility in Methanol very faint turbidity
NMR confirm to structure
物性(参考值)
熔点 177 °C
比旋光度 [α]D -165° (C=2,EtOH)
水溶性 不溶
GHS
象形图 Pictogram Pictogram
信号词 Danger
危险性说明 H302 : Harmful if swallowed.
H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H317 : May cause an allergic skin reaction.
H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled.
防范说明 P501 : Dispose of contents/ container to an approved waste disposal plant.
P261 : Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P272 : Contaminated work clothing should not be allowed out of the workplace.
P270 : Do not eat, drink or smoke when using this product.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ eye protection/ face protection.
P284 : Wear respiratory protection.
P302 + P352 : IF ON SKIN: Wash with plenty of water.
P342 + P311 : If experiencing respiratory symptoms: Call a POISON CENTER/doctor.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P304 + P340 : IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P333 + P313 : If skin irritation or rash occurs: Get medical advice/ attention.
P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
相关法规
RTECS# VA6020000
运输信息
HS编码* 2939.20-000
*此H.S.编码用于日本出口报关,不适用于您所在国家或地区的进口申报
应用
Quinine, an Antimalarial Substance

  Quinine is one of the alkaloids which is included in the bark of cinchona tree and has been researched since 19th century.1) It has an anti-malarial activity2-4) and is considered to inhibit heme polymerase of plasmodium and to indicate toxicity to plasmodium. There are other antimalarial substances such as chloroquine diphosphate [C2301], hydroxychloroquine sulfate [H1306] and artemisinin [A2118]. (The product is for research purpose only)

References


应用
Asymmetric Tandem Michael Addition/Oxidation of Pyrazolones with p-Benzoquinone Using Cinchona Alkaloid Catalysts

B0089,Q0028

Typical Procedure:
p-Benzoquinone (42.6 mg, 0.4 mmol) and quinine (1.3 mg, 2 mol%) are dissolved in 1,2-dichloroethane (2 mL). The solution is stirred at 25 °C for 10 min, after which a 4-substituted pyrazol-5-one (0.2 mmol) is added to the mixture. The solution is stirred at 25 °C for 24 h. Next, the solvent is removed under reduced pressure. The residue is directly subjected to column chromatography (petroleum ether/EtOAc = 10:1–6:1) to afford the desired product.

References


参考文献


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技术规格
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