Maximum quantity allowed is 999
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CAS RN: 10519-96-7 | 产品编码: P2356
Potassium Trimethylsilanolate
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技术规格
| Appearance | White to Almost white powder to crystal |
| Purity(Neutralization titration) | min. 95.0 % |
| NMR | confirm to structure |
物性（参考值）
| 熔点 | 130 °C(dec.) |
GHS
| 象形图 |
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| 信号词 | Danger |
| 危险性说明 | H314 : Causes severe skin burns and eye damage. |
| 防范说明 | P501 : Dispose of contents/ container to an approved waste disposal plant. P260 : Do not breathe dusts or mists. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 : Wash contaminated clothing before reuse. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P405 : Store locked up. |
相关法规
运输信息
| UN编号 | UN3263 |
| 类别 | 8 |
| 包装类别 | II |
| HS编码* | 2931.90-000 |
应用
Silanol Salt for Deprotection Reactions and Cross-coupling Reactions
References
- 1) Metal silanolates: organic soluble equivalents for O−2
- 2) Scope and Limitations of Sodium and Potassium Trimethylsilanolate as Reagents for Conversion of Esters to Carboxylic Acids
- 3) Potassium Trimethylsilanolate Enables Rapid, Homogeneous Suzuki−Miyaura Cross-Coupling of Boronic Esters
- 4) An Additive-Free, Base-Catalyzed Protodesilylation of Organosilanes
- 5) Potassium trimethylsilanolate mediated hydrolysis of nitriles to primary amides
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