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CAS RN: 1058661-78-1 | Product Number: C2347

Chloro[(1,3-dimesitylimidazol-2-ylidene)(N,N-dimethylbenzylamine)palladium(II)]


Purity: >98.0%(T)
Synonyms:
  • SingaCycle™-E1
Product Documents:
200MG
S$57.00
3   0   Contact Us
1G
S$190.50
3   1   Contact Us
5G
S$651.00
9   3   Contact Us

* Please contact our distributors or TCI to order TCI products.
* The storage conditions are subject to change without notice.


Product Number C2347
Purity / Analysis Method >98.0%(T)
Molecular Formula / Molecular Weight C__3__0H__3__6ClN__3Pd = 580.51 
Physical State (20 deg.C) Solid
Storage Temperature Room Temperature (Recommended in a cool and dark place, <15°C)
Packaging and Container 1G-Glass Bottle with Plastic Insert (View image),  200MG-Glass Bottle with Plastic Insert (View image)
CAS RN 1058661-78-1
PubChem Substance ID 87560979
Specifications
Appearance White to Almost white powder to crystal
Purity(Argentometric Titration) min. 98.0 %
Purity(Chelometric back titration) min. 98.0 %
Properties (reference)
GHS
Related Laws:
Transport Information:
H.S.code* 2843.90-000
*This code is applied to the products when TCI exports from Japan and not for import in your country.
Application
N-Heterocyclic Carbene (NHC) Palladium Complex Catalyst

References


Application
SingaCycle(TM)-E1 –Catalyst for the Heck-Mizoroki Reaction

Typical procedure: Aryl Bromide (1 mmol), olefin (1.2 mmol), K2CO3 (2.0 mmol) and 2 mol% NMP solution of SingaCycle(TM)-E1 (400 µL) are added to a vial with a magnetic stir bar. The atmosphere above the reaction mixture is purged with Ar over 30 sec. The vial is closed with a screw cap, and heated at 140°C with vigorous stirring over 18 h. After cooling, the reaction mixtures are filtered under dilution with CH2Cl2 (total: 20 mL). The crude product is loaded directly over a short pad of silica gel and purified by flash chromatography.

References


PubMed Literature


Product Documents (Note: Some products will not have analytical charts available.)
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