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CAS RN: 57842-27-0 | Product Number: B1151
1,3-Benzodithiolylium Tetrafluoroborate [Hydroxyl-Protecting Agent]
![1,3-Benzodithiolylium Tetrafluoroborate [Hydroxyl-Protecting Agent] No-Image](/medias/B1151.jpg?context=bWFzdGVyfHJvb3R8NDI4NzJ8aW1hZ2UvanBlZ3xhRFJoTDJoaU9DODRPVEU1T0RZMk5EQTRPVGt3TDBJeE1UVXhMbXB3Wnd8MzdmOTdiYWNjZjg2Zjk0ZjY3MDk5MTI2ZmM5ZjkwMzlhNjQyY2ZmMDA0MzAzOTdmMmUzZTAyZWU5OWViNDA3OQ)
Purity: >96.0%(T)
Synonyms:
Product Documents:
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Product Number | B1151 |
Purity / Analysis Method | >96.0%(T) |
Molecular Formula / Molecular Weight | C__7H__5BF__4S__2 = 240.04 |
Physical State (20 deg.C) | Solid |
Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
Store Under Inert Gas | Store under inert gas |
Condition to Avoid | Light Sensitive,Moisture Sensitive |
CAS RN | 57842-27-0 |
Reaxys Registry Number | 3578697 |
PubChem Substance ID | 87564092 |
SDBS (AIST Spectral DB) | 50441 |
MDL Number | MFCD00070613 |
Specifications
Appearance | Light yellow to Brown powder to crystal |
Purity(Neutralization titration) | min. 96.0 % |
NMR | confirm to structure |
Properties (reference)
GHS
Pictogram |
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Signal Word | Danger |
Hazard Statements | H302 : Harmful if swallowed. H314 : Causes severe skin burns and eye damage. |
Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P260 : Do not breathe dusts or mists. P270 : Do not eat, drink or smoke when using this product. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 : Wash contaminated clothing before reuse. P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P405 : Store locked up. |
Related Laws:
Transport Information:
UN Number | UN1759 |
Class | 8 |
Packing Group | III |
H.S.code* | 2942.00-000 |
Application
Protection of Hydroxy Groups
References
Cyclic orthoester functions as new protecting groups in nucleosides
M. Sekine, T. Hata, J. Am. Chem. Soc. 1983, 105, 2044.
Synthesis of 2'-O-(1,3-benzodithiol-2-yl)uridine and related compounds as key intermediates in oligoribonucleotide synthesis
M. Sekine, T. Hata, J. Org. Chem. 1983, 48, 3112.
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