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CAS RN: 2314-97-8 | Product Number: T3957
Trifluoroiodomethane (ca. 10％ in Tetrahydrofuran, ca. 0.5mol/L)
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Purity:
Synonyms:
- Trifluoromethyl Iodide (ca. 10％ in Tetrahydrofuran, ca. 0.5mol/L)
- Perfluoromethyl Iodide (ca. 10％ in Tetrahydrofuran, ca. 0.5mol/L)
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 25ML |
$91.00
|
Contact Us | 3 | 18 |
|
| 100ML |
$224.00
|
1 | 4 | 2 |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
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*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
Supplemental Product Information:
Both 25mL and 100mL bottles of this product are attached with a DualSeal (Septum-type Bottle Cap).
For details, please refer to the page "DualSeal (Septum-type Bottle Cap)".
| Product Number | T3957 |
| Molecular Formula / Molecular Weight | CF__3I = 195.91 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature | Refrigerated (0-10°C) |
| Packaging and Container | 100ML-DualSeal Bottle (View image), 25ML-DualSeal Bottle (View image) |
| CAS RN | 2314-97-8 |
| PubChem Substance ID | 468593039 |
Specifications
| Appearance | Colorless to Light yellow clear liquid |
| Concentration(Precipitation Titration) | 9.5 to 11.0 w/w% |
| NMR | confirm to structure |
Properties (reference)
| Specific Gravity (20/20) | 0.97 |
GHS
| Pictogram |
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| Signal Word | Danger |
| Hazard Statements | H302 : Harmful if swallowed. H315 : Causes skin irritation. H319 : Causes serious eye irritation. H371 : May cause damage to organs. H372 : Causes damage to organs through prolonged or repeated exposure. H341 : Suspected of causing genetic defects. H351 : Suspected of causing cancer. H335 : May cause respiratory irritation. H225 : Highly flammable liquid and vapor. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P202 : Do not handle until all safety precautions have been read and understood. P240 : Ground/bond container and receiving equipment. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 : Keep container tightly closed. P201 : Obtain special instructions before use. P243 : Take precautionary measures against static discharge. P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 : Use only non-sparking tools. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P308 + P313 : IF exposed or concerned: Get medical advice/ attention. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P362 : Take off contaminated clothing and wash before reuse. P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. P304 + P340 + P312 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. P403 + P235 : Store in a well-ventilated place. Keep cool. P405 : Store locked up. |
Related Laws:
Transport Information:
| UN Number (DOT-AIR) | UN2056 |
| Class (DOT-AIR) | 3 |
| Packing Group (TCI-A) | II |
| HS Number | 2903.77.0080 |
Application
TCI Practical Example: Trifluoromethylation using Trifluoroiodomethane
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Used Chemicals
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Procedure
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To a solution of 4-bromothiophenol (200 mg, 1.05 mmol) in THF (2 mL) was added NaH (51 mg, 1.27 mmol, 1.2 eq.) slowly at r.t. for 10 min. Then, trifluoroiodomethane (ca. 10% in tetrahydrofuran, ca. 0.5mol/L) (3 mL, 1.59 mmol, 1.5 eq.) was added to the reaction mixture and stirred at the same temperature for overnight. The reaction mixture was diluted with ethyl acetate (25 mL) and washed with water (15 mL) and brine (15 mL), then organic layer was dried over sodium sulfate and filtered. The solvent was removed under reduced pressure and the residue was purified by column chromatography (hexane on silica gel), giving 4-bromophenyl trifluoromethyl sulfide as a colorless liquid (177 mg, 65%).
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Experimenter’s Comments
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The reaction mixture was monitored by UPLC.
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Analytical Data
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4-Bromophenyl Trifluoromethyl Sulfide
1H NMR (270 MHz, CDCl3); δ 7.57 (d, 2H, J = 8.9 Hz), 7.52 (d, 2H, J = 8.4 Hz).
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Lead Reference
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- Convenient synthesis and isolation of trifluoromethylthio-substituted building blocks
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
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Specifications
C of A & Other Certificates
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Analytical Charts
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Other Documents
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