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CAS RN: 1058661-78-1 | Product Number: C2347
Chloro[(1,3-dimesitylimidazol-2-ylidene)(N,N-dimethylbenzylamine)palladium(II)]
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![Chloro[(1,3-dimesitylimidazol-2-ylidene)(N,N-dimethylbenzylamine)palladium(II)]](/_ui/responsive/theme-tci/images/missing_product_zoom.jpg "Chloro[(1,3-dimesitylimidazol-2-ylidene)(N,N-dimethylbenzylamine)palladium(II)]")
Purity: >98.0%(T)
Synonyms:
- SingaCycle™-E1
Product Documents:
| Size | Unit Price | Same Day | 2-3 Business Days | Other Lead Time |
Shipping Information
|
|---|---|---|---|---|---|
| 200MG |
₩70,300
|
3 | 0 | Contact Us | |
| 1G |
₩235,000
|
3 | 1 | Contact Us | |
| 5G |
₩802,900
|
9 | 3 | Contact Us |
* Please contact our distributor of SEJIN CI Co., Ltd.
if you would like to purchase TCI products. The above prices do not include freight cost, customs charge and other charges to the destination. SEJIN CI Co., Ltd. (Phone: 02-2655-2480 / email:
sales@sejinci.co.kr)
* The storage conditions are subject to change without notice.
* The storage conditions are subject to change without notice.
| Product Number | C2347 |
| Purity / Analysis Method | >98.0%(T) |
| Molecular Formula / Molecular Weight | C__3__0H__3__6ClN__3Pd = 580.51 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image), 200MG-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 1058661-78-1 |
| PubChem Substance ID | 87560979 |
Specifications
| Appearance | White to Almost white powder to crystal |
| Purity(Argentometric Titration) | min. 98.0 % |
| Purity(Chelometric back titration) | min. 98.0 % |
Properties (reference)
GHS
Related Laws:
Transport Information:
| H.S.code* | 2843.90-000 |
Application
N-Heterocyclic Carbene (NHC) Palladium Complex Catalyst
References
- Practical Heck?Mizoroki coupling protocol for challenging substrates mediated by an N-heterocyclic carbene-ligated palladacycle
- N-Heterocycle carbene (NHC)-ligated cyclopalladated N,N-dimethylbenzylamine: a highly active, practical and versatile catalyst for the Heck?Mizoroki reaction
Application
SingaCycle(TM)-E1 –Catalyst for the Heck-Mizoroki Reaction
Typical procedure: Aryl Bromide (1 mmol), olefin (1.2 mmol), K2CO3 (2.0 mmol) and 2 mol% NMP solution of SingaCycle(TM)-E1 (400 µL) are added to a vial with a magnetic stir bar. The atmosphere above the reaction mixture is purged with Ar over 30 sec. The vial is closed with a screw cap, and heated at 140°C with vigorous stirring over 18 h. After cooling, the reaction mixtures are filtered under dilution with CH2Cl2 (total: 20 mL). The crude product is loaded directly over a short pad of silica gel and purified by flash chromatography.
References
- E. A. B. Kantchev, G.-R. Peh, C. Zhang, J. Y. Ying, Org. Lett. 2008, 10, 3949.
- G.-R. Peh, E. A. B. Kantchev, C. Zhang, J. Y. Ying, Org. Biomol. Chem. 2009, 7, 2110.
- J. Y. Ying, E. A. B. Kantchev, PCT Int Appl. WO 2008156451 2008.
- E. A. B. Kantchev, J. Y. Ying, Organometallics 2009, 28, 289.
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