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CAS RN: 14781-45-4 | Product Number: H0554
Bis(hexafluoroacetylacetonato)copper(II)
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Purity: >95.0%(T)
Synonyms:
- Copper(II) Hexafluoroacetylacetonate
- Hexafluoroacetylacetono Copper(II) Salt
Product Documents:
| Size | Unit Price | Saitama (Kawaguchi) | Hyogo (Amagasaki) | Stock in other WH |
Shipping Information
|
|---|---|---|---|---|---|
| 1G |
¥4,800
|
11 | 6 | 20 | |
| 5G |
¥12,300
|
5 | 9 | It can be shipped in about 2 weeks after ordering |
* Available Stock: Prompt shipment (for products) in Saitama/Hyogo warehouse. Stock In Other WH: Shipment in about 2-3 Business Days from Saitama warehouse. Please contact us
if you need further information.
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* To send your quote request for bulk quantities, please click on the "Request Bulk Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
* The displayed price is the unit price and does not include consumption tax. The unit prices displayed are the latest and are subject to change without notice.
* To send your quote request for bulk quantities, please click on the "Request Bulk Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
Supplemental Product Information:
Previously this product had been labeled as a hydrate form both in product name and molecular formula. The hydrate form had no exclusive CAS RN and used to share the same CAS RN as the anhydrous form.
To avoid any misleading information and since moisture in product is considered as an impurity, we have decided to remove the term 'Hydrate' from product name and 'xH2O' from the molecular formula for such products.
Please use it at ease since there is no difference in product quality, even if you see the previous indications on a part of label.
| Product Number | H0554 |
| Purity / Analysis Method | >95.0%(T) |
| Molecular Formula / Molecular Weight | C__1__0H__2CuF__1__2O__4 = 477.65 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Hygroscopic |
| Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 14781-45-4 |
| Related CAS RN | 155640-85-0 |
| PubChem Substance ID | 87570941 |
| MDL Number | MFCD00064754 |
Specifications
| Appearance | Green to Dark green powder to crystal |
| Purity(Chelometric Titration) | min. 95.0 %(calcd.on anh.substance) |
| Water | max. 10.0 % |
Properties (reference)
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
Related Laws:
Transport Information:
Application
Copper-catalyzed Cyclopropanation of alpha-Diazoketones to Norcaradienes
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Typical procedure (entry 4): A microwave reaction vessel is charged with a solution of the diazoketone (53 mg) in CH2Cl2 (10 mL). Cu(hfacac)2 (9.5 mg) in CH2Cl2 (2 mL) is added via syringe. The vial is placed in the microwave reactor and heated to 120 °C for 1 minute (ramp from 22 °C to 120 °C requires 2 min). The solvent is removed under reduced pressure, and the residue is purified by flash chromatography (eluent: 0 to 100 % EtOAc/hexanes) to give the norcaradiene (30mg, 64 %) as a white solid.
References
- S. Levin, R. R. Nani, S. E. Reisman, Org. Lett. 2010, 12 , 780.
- S. Levin, R. R. Nani, S. E. Reisman, J. Am. Chem. Soc. 2011, 133 , 774.
Application
Useful Copper Catalyst
Reference
PubMed Literature
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Safety Data Sheet (SDS)
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Specifications
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