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CAS RN: 1155843-79-0 | Product Number: H1404
2-Hydroxy-2-azaadamantane
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Purity: >98.0%(T)
Synonyms:
- AZADOL®
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
Shipping Information
|
|---|---|---|---|---|---|
| 200MG |
€64.00
|
1 | 3 |
|
|
| 1G |
€251.00
|
1 | 10 |
|
|
| 5G |
€981.00
|
4 | 7 |
|
* Stock available in Belgium: Shipment on the same day
* Stock available in Japan: Please check the Shipping Simulation for estimated shipments. (excludes regulated items and dry ice shipments)
Supplemental Product Information:
AZADOL® is a registered trademark of Nissan Chemical Industries, Ltd.
| Product Number | H1404 |
Purity / Analysis Method 
|
>98.0%(T) |
| Molecular Formula / Molecular Weight | C__9H__1__5NO = 153.23 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| Packaging and Container
|
1G-Glass Bottle with Plastic Insert (View image), 200MG-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 1155843-79-0 |
| Reaxys Registry Number | 21286916 |
| PubChem Substance ID | 172089100 |
Specifications
| Appearance | White to Gray to Brown powder to crystal |
| Purity(GC) | min. 97.0 % |
| Purity(Nonaqueous Titration) | min. 98.0 % |
| NMR | confirm to structure |
Properties (reference)
GHS
Related Laws:
Transport Information:
| HS Number | 2933998090 |
Application
AZADO Catalyzed One-Pot Oxidative Cleavage of Vicinal Diols to (Di)Carboxylic Acids
Typical Procedure (R1 = BzO(CH2)7-, R2 = H): To a solution of 9,10-dihydroxydecyl benzoate (30.0 mg, 0.102 mmol) in CH2Cl2 (0.26 mL) and H2O (0.26 mL) is added AZADOL (1.6 mg, 0.0102 mmol) and PhI(OAc)2 (164 mg, 0.510 mmol) at 0 °C. The mixture is allowed to warm to room temperature and stirred for 1 h. Then, 10% HCl is added to the mixture and the resultant solution is extracted with CH2Cl2. The combined organic layer is washed with brine, dried over MgSO4 and concentrated under reduced pressure. The crude product is purified by silica gel column chromatography (eluent: AcOEt/Hexane = 1/8 to only AcOEt) to give 9-(benzoyloxy)nonanoic acid (26.8 mg, 0.0963 mmol, 94%) as white solid.
References
- 1)M. Shibuya, T. Shibuta, H. Fukuda, Y. Iwabuchi, Org. Lett. 2012, 14, 5010.
- 2)A review on AZADO for oxidation of alcohols.
Application
Alcohol Oxidation Catalyst Showing Higher Activity than TEMPO
References
- 1)Y. Iwabuchi, Chem. Pharm. Bull. 2013, 61, 1197.
- 2)M. Shibuya, Y. Sasano, M. Tomizawa, T. Hamada, M. Kozawa, N. Nagahama, Y. Iwabuchi, Synthesis 2011, 3418.
- 3)Y. Iwabuchi, M. Shibuya, M. Tomizawa, Y. Osada, PCT Int. Appl. WO 2009145323, 2009.
- 4)M. Hayashi, M. Shibuya, Y. Iwabuchi, Org. Lett. 2012, 14, 154.
PubMed Literature
Product Articles
[Product Highlights] Alcohol Oxidation Catalyst Showing Higher Activity than TEMPO[Research Articles] AZADO Catalyzed One-Pot Oxidative Cleavage of Vicinal Diols to (Di)Carboxylic Acids
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