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CAS RN: 1807776-35-7 | Product Number: T3443
Tri(cyclohexa-2,5-dien-1-yl)silane
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Purity: >93.0%(GC)
Synonyms:
Product Documents:
| Size | Unit Price | Shanghai | Tianjin | Japan* |
|---|---|---|---|---|
| 200MG |
¥350.00
|
2 | Contact Us | 3 |
| 1G |
¥1,390.00
|
1 | Contact Us | 14 |
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| Product Number | T3443 |
| Purity / Analysis Method | >93.0%(GC) |
| Molecular Formula / Molecular Weight | C__1__8H__2__2Si = 266.46 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Moisture Sensitive |
| Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 1807776-35-7 |
| Reaxys Registry Number | 28704324 |
| PubChem Substance ID | 354333939 |
Specifications
| Appearance | White to Yellow to Orange powder to crystal |
| Purity(GC) | min. 93.0 % |
| Melting point | 63.0 to 68.0 °C |
Properties (reference)
| Melting Point | 66 °C |
GHS
| Pictogram |
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| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
Related Laws:
Transport Information:
| Customs Control Conditions (Q) |
Application
Tri(cyclohexa-2,5-dien-1-yl)silane: A Stable and Easy-to-handle Surrogate of Monosilane (SiH4)
Synthesis of multisubstituted silanes:
In a glove box, a Schlenk tube is charged with an alkene (0.300 mmol). In two vials are weighed B(C6F5)3 (7.7 mg, 15 µmol) and tri(cyclohexa-2,5-dien-1-yl)silane (1, 28.0 mg, 0.105 mmol). All the sealed containers are taken out of the glove box, and the Schlenk tube is connected to a N2 line. Under a N2 counterflow are subsequently added 0.3 mL of CH2Cl2, 1 then B(C6F5)3. The tube is completely sealed and stirred at room temperature for 24 h. After this time, two drops of triethylamine are added to the solution under an N2 counterflow, and the resulting mixture is stirred for 5 min before being filtered over a short alumina column (elution with CH2Cl2). After evaporation of all volatiles, the crude product is purified by flash column chromatography to give the multisubstituted silane 3.
In a glove box, a Schlenk tube is charged with an alkene (0.300 mmol). In two vials are weighed B(C6F5)3 (7.7 mg, 15 µmol) and tri(cyclohexa-2,5-dien-1-yl)silane (1, 28.0 mg, 0.105 mmol). All the sealed containers are taken out of the glove box, and the Schlenk tube is connected to a N2 line. Under a N2 counterflow are subsequently added 0.3 mL of CH2Cl2, 1 then B(C6F5)3. The tube is completely sealed and stirred at room temperature for 24 h. After this time, two drops of triethylamine are added to the solution under an N2 counterflow, and the resulting mixture is stirred for 5 min before being filtered over a short alumina column (elution with CH2Cl2). After evaporation of all volatiles, the crude product is purified by flash column chromatography to give the multisubstituted silane 3.
References
- Formal SiH4 chemistry using stable and easy-to-handle surrogates
PubMed Literature
Articles/Brochures
TCIMAIL
[TCIMAIL No.174] Stable and Easy-to-handle Surrogate of Monosilane (SiH4)[Research Articles] Tri(cyclohexa-2,5-dien-1-yl)silane: A Stable and Easy-to-handle Surrogate of Monosilane (SiH4)
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