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CAS RN: 1208985-45-8 | Product Number: T2579
(1S,4S,5S)-4,7,7-Trimethyl-6-thiabicyclo[3.2.1]octane
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![(1S,4S,5S)-4,7,7-Trimethyl-6-thiabicyclo[3.2.1]octane](/_ui/responsive/theme-tci/images/missing_product_zoom.jpg "(1S,4S,5S)-4,7,7-Trimethyl-6-thiabicyclo[3.2.1]octane")
Purity: >98.0%(GC)
Synonyms:
- (+)-Isothiocineole
Product Documents:
| Size | Unit Price | Shanghai | Tianjin | Japan* |
|---|---|---|---|---|
| 1G |
¥610.00
|
3 | 1 | 20 |
| 5G |
¥1,690.00
|
3 | 1 | 11 |
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| Product Number | T2579 |
| Purity / Analysis Method | >98.0%(GC) |
| Molecular Formula / Molecular Weight | C__1__0H__1__8S = 170.31 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| CAS RN | 1208985-45-8 |
| Reaxys Registry Number | 105189 |
| PubChem Substance ID | 125307479 |
Specifications
| Appearance | Colorless to Almost colorless clear liquid |
| Purity(GC) | min. 98.0 % |
| Optical purity(GC) | min. 97.0 ee% |
| NMR | confirm to structure |
Properties (reference)
| Flash point | 79 °C |
| Specific Rotation | 67° (neat) |
| Refractive Index | 1.52 |
GHS
| Signal Word | Warning |
| Hazard Statements | H227 : Combustible liquid. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P280 : Wear protective gloves/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P403 + P235 : Store in a well-ventilated place. Keep cool. |
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| Customs Control Conditions (Q) |
Application
Chiral Sulfides for Optically Active Three-membered Rings
References
- 1) Practical and Highly Selective Sulfur Ylide Mediated Asymmetric Epoxidations and Aziridinations Using an Inexpensive, Readily Available Chiral Sulfide. Applications to the Synthesis of Quinine and Quinidine
- 2) Asymmetric synthesis of cyclopropyl phosphonates using chiral terpenyl sulfonium and selenonium ylidesw
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