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CAS RN: 108-91-8 | Product Number: C0494
Cyclohexylamine
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Purity: >99.0%(GC)
Synonyms:
Product Documents:
| Size | Unit Price | Shanghai | Tianjin | Japan* |
|---|---|---|---|---|
| 5ML |
¥65.00
|
≥60 | Contact Us | Contact Us |
| 25ML |
¥140.00
|
≥100 | Contact Us | ≥100 |
| 100ML |
¥160.00
|
8 | Contact Us | Contact Us |
| 500ML |
¥210.00
|
28 | Contact Us | ≥100 |
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| Product Number | C0494 |
| Purity / Analysis Method | >99.0%(GC) |
| Molecular Formula / Molecular Weight | C__6H__1__3N = 99.18 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive,Hygroscopic |
| CAS RN | 108-91-8 |
| Reaxys Registry Number | 471175 |
| PubChem Substance ID | 87565613 |
| SDBS (AIST Spectral DB) | 592 |
| Merck Index (14) | 2729 |
| MDL Number | MFCD00001486 |
Specifications
| Appearance | Colorless to Almost colorless clear liquid |
| Purity(GC) | min. 99.0 % |
| Purity(Nonaqueous Titration) | min. 98.0 % |
Properties (reference)
| Melting Point | 18 °C |
| Boiling Point | 135 °C |
| Flash point | 30 °C |
| Specific Gravity (20/20) | 0.87 |
| Refractive Index | 1.46 |
| Solubility in water | Completely miscible |
| Solubility (miscible with) | Alcohol, Ether |
| Solubility (soluble in) | Benzene |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H301 + H311 + H331 : Toxic if swallowed, in contact with skin or if inhaled. H314 : Causes severe skin burns and eye damage. H361 : Suspected of damaging fertility or the unborn child. H370 : Causes damage to organs. H340 : May cause genetic defects. H335 : May cause respiratory irritation. H402 : Harmful to aquatic life. H226 : Flammable liquid and vapor. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P273 : Avoid release to the environment. P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P202 : Do not handle until all safety precautions have been read and understood. P240 : Ground/bond container and receiving equipment. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 : Keep container tightly closed. P201 : Obtain special instructions before use. P243 : Take precautionary measures against static discharge. P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 : Use only non-sparking tools. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor. P361 + P364 : Take off immediately all contaminated clothing and wash it before reuse. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P301 + P310 + P330 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. P403 + P235 : Store in a well-ventilated place. Keep cool. P405 : Store locked up. |
Related Laws:
| CN Number | 942 |
| RTECS# | GX0700000 |
Transport Information:
| UN Number | UN2357 |
| Class | 8 / 3 |
| Packing Group | II |
| Customs Control Conditions (Q) |
Application
Synthesis of a Piperazine Derivative
Synthesis of 1-Cyclohexyl-4-tosylpiperazine
N,N-Bis[2-(p-tolylsulfonyloxy)ethyl]-p-toluenesulfonamide (B4136, 5.83 g, 10.3 mmol), K2CO3 (P1748, 8.00 g, 58.0 mmol), cyclohexylamine (C0494, 0.99 g, 10.0 mmol), and anhydrous CH3CN (50 mL) are added to a round-bottom flask. The mixture is heated to reflux under an N2 atmosphere for 12 h. The mixture is cooled to r.t. and filtered. The filtrate is concentrated, and the residue is purified by flash chromatography (SiO2, CH2Cl2－CH3OH－Et3N as eluent) to give 1-cyclohexyl-4-tosylpiperazine as a white solid in 83% yield (2.67 g).
N,N-Bis[2-(p-tolylsulfonyloxy)ethyl]-p-toluenesulfonamide (B4136, 5.83 g, 10.3 mmol), K2CO3 (P1748, 8.00 g, 58.0 mmol), cyclohexylamine (C0494, 0.99 g, 10.0 mmol), and anhydrous CH3CN (50 mL) are added to a round-bottom flask. The mixture is heated to reflux under an N2 atmosphere for 12 h. The mixture is cooled to r.t. and filtered. The filtrate is concentrated, and the residue is purified by flash chromatography (SiO2, CH2Cl2－CH3OH－Et3N as eluent) to give 1-cyclohexyl-4-tosylpiperazine as a white solid in 83% yield (2.67 g).
References
- One-Step Cyclization: Synthesis of N-Heteroalkyl-N′-tosylpiperazines
PubMed Literature
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