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CAS RN: 34671-83-5 | Product Number: B2496
2,2'-Bipyrimidyl
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Purity: >95.0%(GC)
Synonyms:
- 2,2'-Bipyrimidine
- 2,2'-Dipyrimidyl
Product Documents:
| Size | Unit Price | Shanghai | Tianjin | Japan* |
|---|---|---|---|---|
| 200MG |
¥120.00
|
1 | 1 | 29 |
| 1G |
¥515.00
|
3 | 1 | ≥40 |
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| Product Number | B2496 |
| Purity / Analysis Method | >95.0%(GC) |
| Molecular Formula / Molecular Weight | C__8H__6N__4 = 158.16 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image), 200MG-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 34671-83-5 |
| Reaxys Registry Number | 607396 |
| PubChem Substance ID | 135727183 |
| MDL Number | MFCD00014600 |
Specifications
| Appearance | White to Green to Brown powder to crystal |
| Purity(GC) | min. 95.0 % |
Properties (reference)
| Melting Point | 113 °C |
| Solubility (soluble in) | Methanol |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
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Transport Information:
| Customs Control Conditions (Q) |
Application
Heterodinuclear Metal Complex via Bridging Ligand
2,2'-Bipyrimidyl behaves as a metalloligand like 2,2'-bipyridyls and can be coordinately bonded to two kinds of metals. For example, Fukuzumi et al. have reported the synthesis of a heterodinuclear iridium-ruthenium complex (1) using 2,2'-bipyrimidyl. 1 acts as a catalyst for four-electron reduction of dissolved O2 with formic acid in water. Besides this, Irfanullah and Iftikhar have reported the synthesis of a europium-terbium complex (2) as a heterodilanthanide complex. The luminescence of Eu(III) is enhanced by intramolecular energy transfer from Tb(III) to Eu(III) in the complex.
References
- S. Fukuzumi, T. Kobayashi, T. Suenobu, J. Am. Chem. Soc. 2010, 132, 11866.
- M. Irfanullah, K. Iftikhar, Inorg. Chem. Commun. 2010, 13, 694.
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