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CAS RN: 14647-23-5 | Product Number: B2225

[1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride


Purity: >96.0%(T)
Synonyms:
  • [1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)
  • Dichloro[1,2-bis(diphenylphosphino)ethane]nickel(II)
Product Documents:
1G
¥100.00
6   5   ≥100 
5G
¥305.00
≥40  2   28  
25G
¥490.00
2   7   ≥100 

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Product Number B2225
Purity / Analysis Method >96.0%(T)
Molecular Formula / Molecular Weight C__2__6H__2__4Cl__2NiP__2 = 528.02 
Physical State (20 deg.C) Solid
Storage Temperature Room Temperature (Recommended in a cool and dark place, <15°C)
Packaging and Container 1G-Glass Bottle with Plastic Insert (View image)
CAS RN 14647-23-5
Reaxys Registry Number 14761473
PubChem Substance ID 87565079
MDL Number

MFCD00013313

Specifications
Appearance Orange to Amber to Dark red powder to crystal
Purity(Chelometric Titration) min. 96.0 %
Properties (reference)
GHS
Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H302 + H312 + H332 : Harmful if swallowed, in contact with skin or if inhaled.
H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H372 : Causes damage to organs through prolonged or repeated exposure.
H317 : May cause an allergic skin reaction.
H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H350 : May cause cancer.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P272 : Contaminated work clothing should not be allowed out of the workplace.
P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
P270 : Do not eat, drink or smoke when using this product.
P202 : Do not handle until all safety precautions have been read and understood.
P201 : Obtain special instructions before use.
P271 : Use only outdoors or in a well-ventilated area.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P284 : Wear respiratory protection.
P308 + P313 : IF exposed or concerned: Get medical advice/ attention.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P333 + P313 : If skin irritation or rash occurs: Get medical advice/ attention.
P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
P302 + P352 + P312 : IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/doctor if you feel unwell.
P304 + P340 + P312 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
P405 : Store locked up.
Related Laws:
Transport Information:
Customs Control Conditions (Q)
Application
Controlled Polymerization Catalyst for Catalyst-Transfer Polycondensation (CTCP)
References

R. Miyakoshi, K. Shimono, A. Yokoyama, T. Yokozawa, J. Am. Chem. Soc. 2006, 128, 16012.


PubMed Literature


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