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CAS RN: 91166-50-6 | Product Number: B1773

1,2-Bis[(dimethylamino)dimethylsilyl]ethane [Protecting Reagent for Aromatic Primary Amines]


Purity: >93.0%(GC)
Synonyms:
  • 1,1'-Ethylenebis(N,N,1,1-tetramethylsilanamine)
Product Documents:
5G
¥990.00
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Product Number B1773
Purity / Analysis Method >93.0%(GC)
Molecular Formula / Molecular Weight C__1__0H__2__8N__2Si__2 = 232.52 
Physical State (20 deg.C) Liquid
Storage Temperature Room Temperature (Recommended in a cool and dark place, <15°C)
Store Under Inert Gas Store under inert gas
Condition to Avoid Moisture Sensitive
CAS RN 91166-50-6
Reaxys Registry Number 4366167
PubChem Substance ID 87564668
MDL Number

MFCD00010649

Specifications
Appearance Colorless to Almost colorless clear liquid
Purity(GC) min. 93.0 %
Purity(Nonaqueous Titration) min. 95.0 %
Properties (reference)
Boiling Point 103 °C/13 mmHg
Flash point 13 °C
Specific Gravity (20/20) 0.84
Refractive Index 1.44
GHS
Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H314 : Causes severe skin burns and eye damage.
H225 : Highly flammable liquid and vapor.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P240 : Ground/bond container and receiving equipment.
P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 : Keep container tightly closed.
P243 : Take precautionary measures against static discharge.
P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P242 : Use only non-sparking tools.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P363 : Wash contaminated clothing before reuse.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
P403 + P235 : Store in a well-ventilated place. Keep cool.
P405 : Store locked up.
Related Laws:
Transport Information:
UN Number UN2924
Class 3 / 8
Packing Group II
Customs Control Conditions (Q)
Application
Protection of Substituted Anilines
References

Protection of substituted anilines with 1,1,4,4-tetramethyl-1,4-bis(N,N-dimethylamino)disilethylene

T. L. Guggenheim, Tetrahedron Lett. 1984, 25, 1253.


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