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CAS RN: 16532-02-8 | Product Number: B0847
(Bromomethyl)chlorodimethylsilane
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Purity: >95.0%(GC)
Synonyms:
- Bromomethyldimethylchlorosilane
- BMDMCS
Product Documents:
| Size | Unit Price | Shanghai | Tianjin | Japan* |
|---|---|---|---|---|
| 5G |
¥790.00
|
8 | Contact Us | ≥40 |
| 25G |
¥1,540.00
|
Contact Us | Contact Us | 13 |
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| Product Number | B0847 |
| Purity / Analysis Method | >95.0%(GC) |
| Molecular Formula / Molecular Weight | C__3H__8BrClSi = 187.54 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Moisture Sensitive |
| CAS RN | 16532-02-8 |
| Reaxys Registry Number | 1071201 |
| PubChem Substance ID | 87563828 |
| SDBS (AIST Spectral DB) | 10589 |
| MDL Number | MFCD00000503 |
Specifications
| Appearance | Colorless to Almost colorless clear liquid |
| Purity(GC) | min. 95.0 % |
Properties (reference)
| Boiling Point | 135 °C |
| Flash point | 41 °C |
| Specific Gravity (20/20) | 1.39 |
| Refractive Index | 1.47 |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H314 : Causes severe skin burns and eye damage. H226 : Flammable liquid and vapor. H290 : May be corrosive to metals. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P240 : Ground/bond container and receiving equipment. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 : Keep container tightly closed. P234 : Keep only in original container. P243 : Take precautionary measures against static discharge. P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 : Use only non-sparking tools. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P390 : Absorb spillage to prevent material damage. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 : Wash contaminated clothing before reuse. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P403 + P235 : Store in a well-ventilated place. Keep cool. P406 : Store in corrosive resistant container with a resistant inner liner. P405 : Store locked up. |
Related Laws:
Transport Information:
| UN Number | UN2986 |
| Class | 8 / 3 |
| Packing Group | II |
| Customs Control Conditions (Q) |
Application
Silylating Reagent for GC-ECD
Experimental procedure:
Hexane (1 mL), diethylamine (0.075 mL) and CMDMCS (0.09 mL) are mixed in a sealable vessel and centrifuged. The resulting supernatant (0.4 mL) is added to sample (100 μg) in ethyl acetate (0.1 mL) and refluxed for 30 min at 65 °C. The mixture is then promptly cooled to room temperature followed by adding hexane to adjust to the appropriate concentration. This solution is injected into GC.
Hexane (1 mL), diethylamine (0.075 mL) and CMDMCS (0.09 mL) are mixed in a sealable vessel and centrifuged. The resulting supernatant (0.4 mL) is added to sample (100 μg) in ethyl acetate (0.1 mL) and refluxed for 30 min at 65 °C. The mixture is then promptly cooled to room temperature followed by adding hexane to adjust to the appropriate concentration. This solution is injected into GC.
References
- Gas-chromatographic analysis of insensitive pesticides as their halomethyldimethylsilyl derivatives
PubMed Literature
Articles/Brochures
TCIMAIL
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Safety Data Sheet (SDS)
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