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CAS RN: 996-70-3 | Product Number: T1221
Tetrakis(dimethylamino)ethylene
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Purity: >95.0%(GC)
Synonyms:
- TDAE
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 5G |
£719.00
|
1 | 12 |
|
| 25G |
£3,599.00
|
1 | 2 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | T1221 |
| Purity / Analysis Method | >95.0%(GC) |
| Molecular Formula / Molecular Weight | C__1__0H__2__4N__4 = 200.33 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature | Refrigerated (0-10°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive,Heat Sensitive |
| CAS RN | 996-70-3 |
| Reaxys Registry Number | 1705900 |
| PubChem Substance ID | 87576998 |
| SDBS (AIST Spectral DB) | 21523 |
| MDL Number | MFCD00009601 |
Specifications
| Appearance | Light yellow to Yellow to Orange clear liquid |
| Purity(GC) | min. 95.0 % |
Properties (reference)
| Boiling Point | 59 °C/0.9 mmHg |
| Flash point | 53 °C |
| Specific Gravity (20/20) | 0.87 |
| Refractive Index | 1.48 |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H314 : Causes severe skin burns and eye damage. H226 : Flammable liquid and vapour. |
| Precautionary Statements | P210 : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. |
Related Laws:
| EC Number | 213-638-1 |
Transport Information:
| UN Number | UN2734 |
| Class | 8 / 3 |
| Packing Group | II |
| HS Number | 2921199990 |
Application
An Organic Electron Donor
Tetrakis(dimethylamino)ethylene (TDAE) was first synthesized by Pruett et al.1) It works as an organic electron donor, and is used for various organic reactions.2–4)
References
- 1)Reactions of Polyfluoro Olefins. II. Reactions with Primary and Secondary Amines
- 2)Nucleophilic trifluoromethylation of acyl chlorides using the trifluoromethyl iodide/TDAE reagent
- 3)Original reaction of p-nitrobenzyl chloride with aldehydes using tetrakis(dimethylamino)ethylene (TDAE)
- 4)Reduction of arenediazonium salts by tetrakis(dimethylamino)ethylene (TDAE): Efficient formation of products derived from aryl radicals
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